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  • Poly(dimethylsilylene) thin films were deposited by vacuum evaporation method. Films were measured by infrared absorption spectroscopy, ultraviolet absorption spectroscopy, luminescence and electroluminescence, and results were compared. Vacuum deposited films have character of oligomers, mechanically soft and undergo distortion if electrically contacted. They are well oriented in the perpendicular direction to the substrate and exhibit good luminescence of óó* exciton on wavelength 330−345 nm.. Material tends to recrystallize. Films prepared under electron beam treatment and electron cross beam ionization are cross linked, disordered, firm and mechanically stable. Luminescence intensity is much lower but prepared light emitting diodes are relatively stable.
  • Poly(dimethylsilylene) thin films were deposited by vacuum evaporation method. Films were measured by infrared absorption spectroscopy, ultraviolet absorption spectroscopy, luminescence and electroluminescence, and results were compared. Vacuum deposited films have character of oligomers, mechanically soft and undergo distortion if electrically contacted. They are well oriented in the perpendicular direction to the substrate and exhibit good luminescence of óó* exciton on wavelength 330−345 nm.. Material tends to recrystallize. Films prepared under electron beam treatment and electron cross beam ionization are cross linked, disordered, firm and mechanically stable. Luminescence intensity is much lower but prepared light emitting diodes are relatively stable. (en)
Title
  • Oriented Thin Films of Polysilylenes and their Properties
  • Oriented Thin Films of Polysilylenes and their Properties (en)
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  • Oriented Thin Films of Polysilylenes and their Properties
  • Oriented Thin Films of Polysilylenes and their Properties (en)
skos:notation
  • RIV/00216305:26310/01:PU20291!RIV/2002/MSM/263102/N
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  • 168-176
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  • P(OC 518.20)
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  • 690414
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  • RIV/00216305:26310/01:PU20291
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  • polysilane, luminescence, absorption, infrared spectra (en)
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  • [2614C993C33C]
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  • Brno
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  • Brno
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  • Proceedings of the Workshop Electronic Properties of Molecular Materials and Functional Polymers of EU programme COST 518 Molecular Materials and Functional Polymers for Advanced Devices
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  • Kuřitka, Ivo
  • Salyk, Ota
  • Schauer, František
  • Weiter, Martin
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number of pages
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  • Vysoké učení technické v Brně. Fakulta chemická
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  • 80-214-1893-1
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  • 26310
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