About: Determination of Bismuth by Dielectric Barrier Discharge Atomic Absorption Spectrometry Coupled with Hydride Generation: Method Optimization and Evaluation of Analytical Performance     Goto   Sponge   NotDistinct   Permalink

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  • Atomization of bismuth hydride in a 17 W planar quartz dielectric barrier discharge (DBD) atomizer was optimized and the performance of this device compared to that of a conventional quartz tube atomizer (QTA) for atomic absorption spectrometry (AAS). Free Bi atoms were also observed in the DBD with nitrogen, hydrogen, and helium discharge gases but not in air. The detection limit for Bi is worse than with the QTA. Nevertheless, this hydride generation DBDAAS approach can be used for the routine determination of Bi, providing repeatability and accuracy comparable to that reached with a QTA, as demonstrated by analysis of NIST SRM 1643e (trace elements in water). The potential of in-atomizer preconcentration in a DBD atomizer is outlined.
  • Atomization of bismuth hydride in a 17 W planar quartz dielectric barrier discharge (DBD) atomizer was optimized and the performance of this device compared to that of a conventional quartz tube atomizer (QTA) for atomic absorption spectrometry (AAS). Free Bi atoms were also observed in the DBD with nitrogen, hydrogen, and helium discharge gases but not in air. The detection limit for Bi is worse than with the QTA. Nevertheless, this hydride generation DBDAAS approach can be used for the routine determination of Bi, providing repeatability and accuracy comparable to that reached with a QTA, as demonstrated by analysis of NIST SRM 1643e (trace elements in water). The potential of in-atomizer preconcentration in a DBD atomizer is outlined. (en)
Title
  • Determination of Bismuth by Dielectric Barrier Discharge Atomic Absorption Spectrometry Coupled with Hydride Generation: Method Optimization and Evaluation of Analytical Performance
  • Determination of Bismuth by Dielectric Barrier Discharge Atomic Absorption Spectrometry Coupled with Hydride Generation: Method Optimization and Evaluation of Analytical Performance (en)
skos:prefLabel
  • Determination of Bismuth by Dielectric Barrier Discharge Atomic Absorption Spectrometry Coupled with Hydride Generation: Method Optimization and Evaluation of Analytical Performance
  • Determination of Bismuth by Dielectric Barrier Discharge Atomic Absorption Spectrometry Coupled with Hydride Generation: Method Optimization and Evaluation of Analytical Performance (en)
skos:notation
  • RIV/00216305:26220/14:PU111224!RIV15-MSM-26220___
http://linked.open...avai/riv/aktivita
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  • I, S
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  • 86
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  • 10739
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  • RIV/00216305:26220/14:PU111224
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  • dielectric barrier discharge, DBD, atomic absorption spektrometry, AAS, quartz tube atomizér, QTA (en)
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  • US - Spojené státy americké
http://linked.open...ontrolniKodProRIV
  • [84BF3D335975]
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  • ANALYTICAL CHEMISTRY
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  • 2014
http://linked.open...iv/tvurceVysledku
  • Boušek, Jaroslav
issn
  • 0003-2700
number of pages
http://bibframe.org/vocab/doi
  • 10.1021/ac502093y
http://localhost/t...ganizacniJednotka
  • 26220
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