About: Deamination of N -} Sn-Coordinated Organotin(II) Hydroxide: Formation of a New C-O Covalent Bond     Goto   Sponge   NotDistinct   Permalink

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Description
  • The synthesis of the pentacarbonylchromium complex [{2,6-(Me2NCH2)(2)C6H3}(Cl) SnCr(CO)(5)] is reported. Starting with this compound, organotin(II) pentacarbonylchromium methoxide [{2,6-(Me2NCH2)(2)C6H3}(OMe)SnCr(CO)(5)] was prepared and used for the synthesis of dimeric N -} Sn intramolecularly coordinated organotin(II) pentacarbonylchromium hydroxide [{2,6-(Me2NCH2)(2)C6H3}Sn(mu-OH)Cr(CO)(5)](2) by easy hydrolytic protocol. In addition, acid-base-type reaction of this latter compound with HOTf provided unprecedented cyclization product [6-(Me2NCH2)-2,3-(C6H3CH2OSn)Cr-(CO)(5)](2). The cyclization process is accompanied by the formation of a new C-O covalent bond along with the elimination of Me2NH.
  • The synthesis of the pentacarbonylchromium complex [{2,6-(Me2NCH2)(2)C6H3}(Cl) SnCr(CO)(5)] is reported. Starting with this compound, organotin(II) pentacarbonylchromium methoxide [{2,6-(Me2NCH2)(2)C6H3}(OMe)SnCr(CO)(5)] was prepared and used for the synthesis of dimeric N -} Sn intramolecularly coordinated organotin(II) pentacarbonylchromium hydroxide [{2,6-(Me2NCH2)(2)C6H3}Sn(mu-OH)Cr(CO)(5)](2) by easy hydrolytic protocol. In addition, acid-base-type reaction of this latter compound with HOTf provided unprecedented cyclization product [6-(Me2NCH2)-2,3-(C6H3CH2OSn)Cr-(CO)(5)](2). The cyclization process is accompanied by the formation of a new C-O covalent bond along with the elimination of Me2NH. (en)
Title
  • Deamination of N -} Sn-Coordinated Organotin(II) Hydroxide: Formation of a New C-O Covalent Bond
  • Deamination of N -} Sn-Coordinated Organotin(II) Hydroxide: Formation of a New C-O Covalent Bond (en)
skos:prefLabel
  • Deamination of N -} Sn-Coordinated Organotin(II) Hydroxide: Formation of a New C-O Covalent Bond
  • Deamination of N -} Sn-Coordinated Organotin(II) Hydroxide: Formation of a New C-O Covalent Bond (en)
skos:notation
  • RIV/00216275:25310/14:39898824!RIV15-MSM-25310___
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • I
http://linked.open...iv/cisloPeriodika
  • 31
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 9906
http://linked.open...ai/riv/idVysledku
  • RIV/00216275:25310/14:39898824
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • Bond; Covalent; C-O; New; Formation; Hydroxide; OrganotinII; Sn-Coordinated; Deamination (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • DE - Spolková republika Německo
http://linked.open...ontrolniKodProRIV
  • [3EFE90C44D7B]
http://linked.open...i/riv/nazevZdroje
  • European Journal of Inorganic Chemistry
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 2014
http://linked.open...iv/tvurceVysledku
  • Dostál, Libor
  • Jambor, Roman
  • Růžička, Aleš
http://linked.open...ain/vavai/riv/wos
  • 000344791100001
issn
  • 1434-1948
number of pages
http://bibframe.org/vocab/doi
  • 10.1002/ejic.201402836
http://localhost/t...ganizacniJednotka
  • 25310
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