About: Intramolecularly C,N-Coordinated Homo- and Heteroleptic Organostannylenes

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	The synthesis of the C,N-chelated homoleptic organotetrylenes (L1)2E (1, E = Sn; 2, E = Pb) and of the tungsten pentacarbonyl complex (L1)2SnW(CO)5 (3), containing the sterically demanding C,N-chelating ligand L1 (L1 = [2-{(C6H3-2,6-Pri2)N?CH}C6H4]?) is reported. In contrast, the use of the C,N-chelated ligand L2 (L2 = [2-{(C6H3-2,6-Pri2)N?C(Me)}C6H2(OCH2O)]?) provided either the homoleptic stannylene (L2)2Sn (4) or the C,N-chelated chlorostannylene (L2)SnCl (5). All attempts to convert the latter into the corresponding ditin compound [L2Sn]2 failed, however, and resulted in the isolation of 4 and elemental tin. These attempts also provided the unprecedented complex [2-{(C6H3-2,6-Pri2)N?C(Me)}C6H2(OCH2O)][2-{(C6H3-2,6-Pri2)NHCH(Me)}C6H2(OCH2O)]Sn (6). The synthesis of the C,N-chelated homoleptic organotetrylenes (L1)2E (1, E = Sn; 2, E = Pb) and of the tungsten pentacarbonyl complex (L1)2SnW(CO)5 (3), containing the sterically demanding C,N-chelating ligand L1 (L1 = [2-{(C6H3-2,6-Pri2)N?CH}C6H4]?) is reported. In contrast, the use of the C,N-chelated ligand L2 (L2 = [2-{(C6H3-2,6-Pri2)N?C(Me)}C6H2(OCH2O)]?) provided either the homoleptic stannylene (L2)2Sn (4) or the C,N-chelated chlorostannylene (L2)SnCl (5). All attempts to convert the latter into the corresponding ditin compound [L2Sn]2 failed, however, and resulted in the isolation of 4 and elemental tin. These attempts also provided the unprecedented complex [2-{(C6H3-2,6-Pri2)N?C(Me)}C6H2(OCH2O)][2-{(C6H3-2,6-Pri2)NHCH(Me)}C6H2(OCH2O)]Sn (6). (en)
Title	Intramolecularly C,N-Coordinated Homo- and Heteroleptic Organostannylenes Intramolecularly C,N-Coordinated Homo- and Heteroleptic Organostannylenes (en)
skos:prefLabel	Intramolecularly C,N-Coordinated Homo- and Heteroleptic Organostannylenes Intramolecularly C,N-Coordinated Homo- and Heteroleptic Organostannylenes (en)
skos:notation	RIV/00216275:25310/14:39898823!RIV15-MSM-25310___
http://linked.open...avai/riv/aktivita	I P
http://linked.open...avai/riv/aktivity	I, P(GA13-00289S)
http://linked.open...iv/cisloPeriodika	23
http://linked.open...vai/riv/dodaniDat	2015
http://linked.open...aciTvurceVysledku	Dostál, Libor Růžička, Aleš Jambor, Roman Bouška, Marek Novák, Miroslav
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Univerzita Pardubice / Fakulta chemicko-technologická
http://linked.open...dnocenehoVysledku	22604
http://linked.open...ai/riv/idVysledku	RIV/00216275:25310/14:39898823
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	Organostannylenes; Heteroleptic; and; Homo-; C,N-Coordinated; Intramolecularly (en)
http://linked.open.../riv/klicoveSlovo	Heteroleptic Homo- Intramolecularly N-Coordinated Organostannylenes and C
http://linked.open...odStatuVydavatele	US - Spojené státy americké
http://linked.open...ontrolniKodProRIV	[C685B64391F0]
http://linked.open...i/riv/nazevZdroje	Organometallics
http://linked.open...in/vavai/riv/obor	CA
http://linked.open...ichTvurcuVysledku	5 (xsd:int)
http://linked.open...cetTvurcuVysledku	5 (xsd:int)
http://linked.open...vavai/riv/projekt	Heteroboroxines-A New Class of Boroxine Based Compounds
http://linked.open...UplatneniVysledku	2014
http://linked.open...v/svazekPeriodika	33
http://linked.open...iv/tvurceVysledku	Dostál, Libor Jambor, Roman Novák, Miroslav Růžička, Aleš Bouška, Marek
http://linked.open...ain/vavai/riv/wos	000346114900010
issn	0276-7333
number of pages	7 (xsd:int)
http://bibframe.org/vocab/doi	10.1021/om500698k
http://localhost/t...ganizacniJednotka	25310

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