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  • The reactivity and complexation properties of dicoordinated Sn(II) and Sn(0) compounds are reviewed. The (dominant) electrophilicity of the stannylenes was confirmed and quantified through density functional theory (DFT) based reactivity indices. For these compounds, combining theoretical DFT calculations and experimental nuclear magnetic resonance (NMR) spectroscopic results has evidenced their potential to undergo pi-complexation from aromatic pi clouds in addition to significantly stronger sigma-complexation. Moreover, their potential as Lewis bases was scrutinized in their interactions and reactions with iron and tungsten carbonyl Lewis acids. Finally, a prospective comparison of the reactivity of divalent stannylenes and stannylones, with a 0 oxidation state at the Sn atom, is presented.
  • The reactivity and complexation properties of dicoordinated Sn(II) and Sn(0) compounds are reviewed. The (dominant) electrophilicity of the stannylenes was confirmed and quantified through density functional theory (DFT) based reactivity indices. For these compounds, combining theoretical DFT calculations and experimental nuclear magnetic resonance (NMR) spectroscopic results has evidenced their potential to undergo pi-complexation from aromatic pi clouds in addition to significantly stronger sigma-complexation. Moreover, their potential as Lewis bases was scrutinized in their interactions and reactions with iron and tungsten carbonyl Lewis acids. Finally, a prospective comparison of the reactivity of divalent stannylenes and stannylones, with a 0 oxidation state at the Sn atom, is presented. (en)
Title
  • Reactivity of low-oxidation state tin compounds: an overview of the benefits of combining DFT Theory and experimental NMR spectroscopy
  • Reactivity of low-oxidation state tin compounds: an overview of the benefits of combining DFT Theory and experimental NMR spectroscopy (en)
skos:prefLabel
  • Reactivity of low-oxidation state tin compounds: an overview of the benefits of combining DFT Theory and experimental NMR spectroscopy
  • Reactivity of low-oxidation state tin compounds: an overview of the benefits of combining DFT Theory and experimental NMR spectroscopy (en)
skos:notation
  • RIV/00216275:25310/14:39898451!RIV15-GA0-25310___
http://linked.open...avai/riv/aktivita
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  • P(GAP207/12/0223)
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  • 6
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  • 41439
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  • RIV/00216275:25310/14:39898451
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  • reactivity; stannylenes and stannylones; conceptual density functional theory; Sn-119 NMR spectroscopy; dicoordinate tin compounds (en)
http://linked.open.../riv/klicoveSlovo
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  • CA - Kanada
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  • [2209988D9947]
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  • Canadian Journal of Chemistry - Revue Canadienne de Chimie
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  • 92
http://linked.open...iv/tvurceVysledku
  • Růžička, Aleš
  • Turek, Jan
  • Broeckaert, Lies
  • De Proft, Frank
  • Willem, Rudolph
http://linked.open...ain/vavai/riv/wos
  • 000343115500005
issn
  • 0008-4042
number of pages
http://bibframe.org/vocab/doi
  • 10.1139/cjc-2013-0521
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  • 25310
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