About: Manganese(II) one-dimensional coordination polymers with nitrobenzoato or nitrosalicylato bridges: Syntheses, crystal structures, and magnetic properties     Goto   Sponge   NotDistinct   Permalink

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  • Five polymeric Mn(II) complexes with bridging carboxylato groups were prepared and structurally characterized. The bridging carboxylato ligand in double-chain coordination polymeric structures of [Mn(mu-3-NO(2)bz)(2) (bipy)](n)center dot nH(2)O, [Mn(mu-3,5-(NO2)(2)bz)(2)(bipy)](n), [Mn(mu-5-(NO2)sal)(2)(bipy)](n), and [Mn(mu-5-(NO2)sal)(2)(phen)](n), where 3-NO(2)bz(-) = 3-nitrobenzoate, 3,5-(NO2)(2)bz(-) = 3,5-dinitrobenzoate, 5-(NO2)sal(-) = 5-nitrosalicylate, bipy = 2,2'-bipyridine and phen = 1,10-phenanthroline, exhibits the syn-anti bidentate bridging mode. The Mn(II) atom in the coordination polymer [Mn(mu-4-NO(2)bz)(4-NO(2)bz)(phen)(H2O)](n), where 4-NO(2)b(z) = 3-nitrobenzoate, is coordinated by terminal carboxylato groups in the syn monodentate mode but two Mn(II) atoms are connected with bridging 4-nitrobenzoate ligands in the anti-anti bidentate bridging mode. The magnetic susceptibility and magnetization data confirm that weak exchange interactions of an antiferromagnetic nature apply in these complexes.
  • Five polymeric Mn(II) complexes with bridging carboxylato groups were prepared and structurally characterized. The bridging carboxylato ligand in double-chain coordination polymeric structures of [Mn(mu-3-NO(2)bz)(2) (bipy)](n)center dot nH(2)O, [Mn(mu-3,5-(NO2)(2)bz)(2)(bipy)](n), [Mn(mu-5-(NO2)sal)(2)(bipy)](n), and [Mn(mu-5-(NO2)sal)(2)(phen)](n), where 3-NO(2)bz(-) = 3-nitrobenzoate, 3,5-(NO2)(2)bz(-) = 3,5-dinitrobenzoate, 5-(NO2)sal(-) = 5-nitrosalicylate, bipy = 2,2'-bipyridine and phen = 1,10-phenanthroline, exhibits the syn-anti bidentate bridging mode. The Mn(II) atom in the coordination polymer [Mn(mu-4-NO(2)bz)(4-NO(2)bz)(phen)(H2O)](n), where 4-NO(2)b(z) = 3-nitrobenzoate, is coordinated by terminal carboxylato groups in the syn monodentate mode but two Mn(II) atoms are connected with bridging 4-nitrobenzoate ligands in the anti-anti bidentate bridging mode. The magnetic susceptibility and magnetization data confirm that weak exchange interactions of an antiferromagnetic nature apply in these complexes. (en)
Title
  • Manganese(II) one-dimensional coordination polymers with nitrobenzoato or nitrosalicylato bridges: Syntheses, crystal structures, and magnetic properties
  • Manganese(II) one-dimensional coordination polymers with nitrobenzoato or nitrosalicylato bridges: Syntheses, crystal structures, and magnetic properties (en)
skos:prefLabel
  • Manganese(II) one-dimensional coordination polymers with nitrobenzoato or nitrosalicylato bridges: Syntheses, crystal structures, and magnetic properties
  • Manganese(II) one-dimensional coordination polymers with nitrobenzoato or nitrosalicylato bridges: Syntheses, crystal structures, and magnetic properties (en)
skos:notation
  • RIV/00216275:25310/14:39898441!RIV15-MSM-25310___
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • I
http://linked.open...iv/cisloPeriodika
  • September
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
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  • 27125
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  • RIV/00216275:25310/14:39898441
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  • Coordination polymer; EPR spectroscopy; Magnetic properties; Crystal structures; Manganese (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • GB - Spojené království Velké Británie a Severního Irska
http://linked.open...ontrolniKodProRIV
  • [00E2CAF90DBD]
http://linked.open...i/riv/nazevZdroje
  • Polyhedron
http://linked.open...in/vavai/riv/obor
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http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 79
http://linked.open...iv/tvurceVysledku
  • Moncol, Jan
  • Padělková, Zdeňka
  • Valigura, Dusan
  • Valko, Marian
  • Boca, Roman
  • Cechova, Danica
  • Dlhan, L'ubor
  • Gala, Lukas
  • Martiskova, Alena
http://linked.open...ain/vavai/riv/wos
  • 000340313800016
issn
  • 0277-5387
number of pages
http://bibframe.org/vocab/doi
  • 10.1016/j.poly.2014.05.005
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  • 25310
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