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rdf:type
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Description
| - Two mixed amido-azido tin(IV) species bearing either C,N-chelating or bulky amido ligands were prepared by the reaction of the corresponding stannylene (e.g., Sn[N(SiMe3)(2)](2) (1) or (L-CN)(2)Sn (2, L-CN = 2-(N,N-dimethylaminomethyl)phenyl)) with Me3SiN3. Both products of the oxidative addition, Sn[N(SiMe3)(2)](3)N-3 (3) and (L-CN)(2)Sn[N(SiMe3)(2)]N-3 (5), respectively, were fully characterized by both multinuclear NMR spectroscopy and XRD analysis. Heating of a mixture of 2 and Me3SiN3 up to 100 degrees C lead to the formation of a novel dimeric species (L-CN)(2)Sn(mu-NSiMe3)(2)Sn(L-CN)(2) (4), where the two tin atoms are bridged by two NSiMe3 ligands, thus forming a four-membered diazadistannacycle. DFT calculations were also carried out to support the proposed reaction mechanisms.
- Two mixed amido-azido tin(IV) species bearing either C,N-chelating or bulky amido ligands were prepared by the reaction of the corresponding stannylene (e.g., Sn[N(SiMe3)(2)](2) (1) or (L-CN)(2)Sn (2, L-CN = 2-(N,N-dimethylaminomethyl)phenyl)) with Me3SiN3. Both products of the oxidative addition, Sn[N(SiMe3)(2)](3)N-3 (3) and (L-CN)(2)Sn[N(SiMe3)(2)]N-3 (5), respectively, were fully characterized by both multinuclear NMR spectroscopy and XRD analysis. Heating of a mixture of 2 and Me3SiN3 up to 100 degrees C lead to the formation of a novel dimeric species (L-CN)(2)Sn(mu-NSiMe3)(2)Sn(L-CN)(2) (4), where the two tin atoms are bridged by two NSiMe3 ligands, thus forming a four-membered diazadistannacycle. DFT calculations were also carried out to support the proposed reaction mechanisms. (en)
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Title
| - Comparison of reactivity of C,N-chelated and Lappert's stannylenes with trimethylsilylazide
- Comparison of reactivity of C,N-chelated and Lappert's stannylenes with trimethylsilylazide (en)
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skos:prefLabel
| - Comparison of reactivity of C,N-chelated and Lappert's stannylenes with trimethylsilylazide
- Comparison of reactivity of C,N-chelated and Lappert's stannylenes with trimethylsilylazide (en)
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skos:notation
| - RIV/00216275:25310/14:39898439!RIV15-GA0-25310___
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http://linked.open...avai/riv/aktivita
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http://linked.open...avai/riv/aktivity
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http://linked.open...iv/cisloPeriodika
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http://linked.open...vai/riv/dodaniDat
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http://linked.open...aciTvurceVysledku
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http://linked.open.../riv/druhVysledku
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http://linked.open...iv/duvernostUdaju
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http://linked.open...titaPredkladatele
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http://linked.open...dnocenehoVysledku
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http://linked.open...ai/riv/idVysledku
| - RIV/00216275:25310/14:39898439
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http://linked.open...riv/jazykVysledku
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http://linked.open.../riv/klicovaSlova
| - DFT calculations; XRD analysis; NMR spectroscopy; L-CN ligand; tin(IV) azide (en)
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http://linked.open.../riv/klicoveSlovo
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http://linked.open...odStatuVydavatele
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http://linked.open...ontrolniKodProRIV
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http://linked.open...i/riv/nazevZdroje
| - Canadian Journal of Chemistry - Revue Canadienne de Chimie
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http://linked.open...in/vavai/riv/obor
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http://linked.open...ichTvurcuVysledku
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http://linked.open...cetTvurcuVysledku
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http://linked.open...vavai/riv/projekt
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http://linked.open...UplatneniVysledku
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http://linked.open...v/svazekPeriodika
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http://linked.open...iv/tvurceVysledku
| - Padělková, Zdeňka
- Růžička, Aleš
- Švec, Petr
- De Proft, Frank
- Alonso, Mercedes
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http://linked.open...ain/vavai/riv/wos
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issn
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number of pages
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http://bibframe.org/vocab/doi
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http://localhost/t...ganizacniJednotka
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