About: Structural diversity of two 1,2,4-triazole based N-heterocyclic carbene complexes of silver(I)     Goto   Sponge   NotDistinct   Permalink

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  • Two silver(I) complexes of the [(NHC)(2)Ag]Y-+(-) type bearing two different triazole-based N-heterocyclic carbene (NHC) ligands, [1-tert-butyl-4-(2-methoxyphenyl)-3-phenyl-1H-1,2,4-triazol-4-ium-5-ylidene and 1 -tert-butyl-4-(4-methylphenyl)-3-phenyl-1H-1,2,4-triazol-4-ium-5-ylidene], were synthesized according to the modified 'silver salt method. The characterization of the respective complexes in solution by NMR spectroscopy, as well as in solid state by X-ray diffraction techniques, revealed the formation of two different complexes with either an anti or a syn geometry.
  • Two silver(I) complexes of the [(NHC)(2)Ag]Y-+(-) type bearing two different triazole-based N-heterocyclic carbene (NHC) ligands, [1-tert-butyl-4-(2-methoxyphenyl)-3-phenyl-1H-1,2,4-triazol-4-ium-5-ylidene and 1 -tert-butyl-4-(4-methylphenyl)-3-phenyl-1H-1,2,4-triazol-4-ium-5-ylidene], were synthesized according to the modified 'silver salt method. The characterization of the respective complexes in solution by NMR spectroscopy, as well as in solid state by X-ray diffraction techniques, revealed the formation of two different complexes with either an anti or a syn geometry. (en)
Title
  • Structural diversity of two 1,2,4-triazole based N-heterocyclic carbene complexes of silver(I)
  • Structural diversity of two 1,2,4-triazole based N-heterocyclic carbene complexes of silver(I) (en)
skos:prefLabel
  • Structural diversity of two 1,2,4-triazole based N-heterocyclic carbene complexes of silver(I)
  • Structural diversity of two 1,2,4-triazole based N-heterocyclic carbene complexes of silver(I) (en)
skos:notation
  • RIV/00216275:25310/14:39898438!RIV15-GA0-25310___
http://linked.open...avai/riv/aktivita
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  • P(GAP207/12/0223)
http://linked.open...iv/cisloPeriodika
  • October
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  • 47857
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  • RIV/00216275:25310/14:39898438
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  • Silver complexes; N-heterocyclic carbene triazole (en)
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  • NL - Nizozemsko
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  • [88575B39233F]
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  • Inorganic Chemistry Communications
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  • 48
http://linked.open...iv/tvurceVysledku
  • Růžička, Aleš
  • Turek, Jan
  • Růžičková, Zdeňka
http://linked.open...ain/vavai/riv/wos
  • 000343362500025
issn
  • 1387-7003
number of pages
http://bibframe.org/vocab/doi
  • 10.1016/j.inoche.2014.08.019
http://localhost/t...ganizacniJednotka
  • 25310
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