About: N,N-dimethylamino-phenylene-acetylene scaffolding: Structure-property relationships     Goto   Sponge   NotDistinct   Permalink

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Description
  • Seven model donor-substituted phenyleneethynylene molecules with up to three 1,4-phenylene and two acetylenic units were synthesized by Suzuki-Miyaura and Sonogashira cross-coupling reactions and further studied by absorption and emission spectra and theoretical calculations. The pi-system between the N,N-dimethylamino group and terminal acetylene was systematically elongated which allowed elucidation of the fundamental structure-property relationships. Structural factors such as molecular length and chromophore planarity proved to be crucial for the observed spectroscopic behavior.
  • Seven model donor-substituted phenyleneethynylene molecules with up to three 1,4-phenylene and two acetylenic units were synthesized by Suzuki-Miyaura and Sonogashira cross-coupling reactions and further studied by absorption and emission spectra and theoretical calculations. The pi-system between the N,N-dimethylamino group and terminal acetylene was systematically elongated which allowed elucidation of the fundamental structure-property relationships. Structural factors such as molecular length and chromophore planarity proved to be crucial for the observed spectroscopic behavior. (en)
Title
  • N,N-dimethylamino-phenylene-acetylene scaffolding: Structure-property relationships
  • N,N-dimethylamino-phenylene-acetylene scaffolding: Structure-property relationships (en)
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  • N,N-dimethylamino-phenylene-acetylene scaffolding: Structure-property relationships
  • N,N-dimethylamino-phenylene-acetylene scaffolding: Structure-property relationships (en)
skos:notation
  • RIV/00216275:25310/14:39898171!RIV15-GA0-25310___
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  • RIV/00216275:25310/14:39898171
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  • Donor; Emission; Absorption; pi-System; Phenylene; Acetylene (en)
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  • 108
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  • Bureš, Filip
  • Nepraš, Miloš
  • Přichystalová, Hana
  • Almonasy, Numan
  • Grampp, Guenter
http://linked.open...ain/vavai/riv/wos
  • 000338002200007
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  • 0143-7208
number of pages
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  • 10.1016/j.dyepig.2014.04.018
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  • 25310
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