About: Cyclopentadienyl and indenyl molybdenum(II) complexes bearing planar N,N,N-chelating ligands

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About: Cyclopentadienyl and indenyl molybdenum(II) complexes bearing planar N,N,N-chelating ligands Goto Sponge NotDistinct Permalink

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	The reactivity of cyclopentadienyl and indenyl molybdenum(II) complexes [(h5-Cp')Mo(CO)2(NCMe)2] [BF4] (Cp' = Cp, Ind, 1,3-Ph2C9H5) with a series of planar N,N,N-chelating ligands was scrutinized. In particular cases a spontaneous release of carbon monoxide to give [(h5-Cp')Mo(CO)(k3-N,N,NL)][BF4] depending on several factors including the basicity of the tridentate ligand as well as the nature of the starting molybdenum(II) compound. This behaviour strongly contrasts with tripodal ligands those do not affect cis-Mo(CO)2 moiety even upon tridentate coordination. All structure types, discussed in this work, were elucidated by the spectroscopic measurements as well as by the X-ray crystallography. The reactivity of cyclopentadienyl and indenyl molybdenum(II) complexes [(h5-Cp')Mo(CO)2(NCMe)2] [BF4] (Cp' = Cp, Ind, 1,3-Ph2C9H5) with a series of planar N,N,N-chelating ligands was scrutinized. In particular cases a spontaneous release of carbon monoxide to give [(h5-Cp')Mo(CO)(k3-N,N,NL)][BF4] depending on several factors including the basicity of the tridentate ligand as well as the nature of the starting molybdenum(II) compound. This behaviour strongly contrasts with tripodal ligands those do not affect cis-Mo(CO)2 moiety even upon tridentate coordination. All structure types, discussed in this work, were elucidated by the spectroscopic measurements as well as by the X-ray crystallography. (en)
Title	Cyclopentadienyl and indenyl molybdenum(II) complexes bearing planar N,N,N-chelating ligands Cyclopentadienyl and indenyl molybdenum(II) complexes bearing planar N,N,N-chelating ligands (en)
skos:prefLabel	Cyclopentadienyl and indenyl molybdenum(II) complexes bearing planar N,N,N-chelating ligands Cyclopentadienyl and indenyl molybdenum(II) complexes bearing planar N,N,N-chelating ligands (en)
skos:notation	RIV/00216275:25310/14:39898096!RIV15-MSM-25310___
http://linked.open...avai/riv/aktivita	I
http://linked.open...avai/riv/aktivity	I
http://linked.open...iv/cisloPeriodika	December
http://linked.open...vai/riv/dodaniDat	2015
http://linked.open...aciTvurceVysledku	Honzíčková, Iva Vinklárek, Jaromír Padělková, Zdeňka Honzíček, Jan
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Univerzita Pardubice / Fakulta chemicko-technologická
http://linked.open...dnocenehoVysledku	9516
http://linked.open...ai/riv/idVysledku	RIV/00216275:25310/14:39898096
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	CO-releasing molecule; Infrared spectroscopy; Pincer ligands; Indenyl effect; Molybdenum compounds (en)
http://linked.open.../riv/klicoveSlovo	Infrared spectroscopy CO-releasing molecule Indenyl effect Molybdenum compounds Pincer ligands
http://linked.open...odStatuVydavatele	CH - Švýcarská konfederace
http://linked.open...ontrolniKodProRIV	[8AFDCEB2A408]
http://linked.open...i/riv/nazevZdroje	Journal of Organometallic Chemistry
http://linked.open...in/vavai/riv/obor	CA
http://linked.open...ichTvurcuVysledku	4 (xsd:int)
http://linked.open...cetTvurcuVysledku	4 (xsd:int)
http://linked.open...UplatneniVysledku	2014
http://linked.open...v/svazekPeriodika	772-773
http://linked.open...iv/tvurceVysledku	Vinklárek, Jaromír Honzíček, Jan Honzíčková, Iva Růžičková, Zdeňka
http://linked.open...ain/vavai/riv/wos	000344470100040
issn	0022-328X
number of pages	8 (xsd:int)
http://bibframe.org/vocab/doi	10.1016/j.jorganchem.2014.09.028
http://localhost/t...ganizacniJednotka	25310

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