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  • Absorption/emission and electrochem. properties of four new quadrupolar push-pull-push mols. with central tetrafluorobenzene acceptor and two peripheral N,N-dihexylamino and O-hexyloxy donor groups were investigated. Exptl. data were completed with quantum-chem. calcns. The extent of the intramol. charge-transfer and nonlinear optical properties were elucidated in terms of structure-property relationships. The electronic nature of the appended donor group, length, planarity and compn. of the pí-linker (combination of 1,4-phenylene, 2,5-thienylene and acetylenic subunits) are the most important factors affecting the linear as well as nonlinear optical properties.
  • Absorption/emission and electrochem. properties of four new quadrupolar push-pull-push mols. with central tetrafluorobenzene acceptor and two peripheral N,N-dihexylamino and O-hexyloxy donor groups were investigated. Exptl. data were completed with quantum-chem. calcns. The extent of the intramol. charge-transfer and nonlinear optical properties were elucidated in terms of structure-property relationships. The electronic nature of the appended donor group, length, planarity and compn. of the pí-linker (combination of 1,4-phenylene, 2,5-thienylene and acetylenic subunits) are the most important factors affecting the linear as well as nonlinear optical properties. (en)
Title
  • Spectral, electrochemical and calculated properties of quadrupolar chromophores based on tetrafluorobenzene
  • Spectral, electrochemical and calculated properties of quadrupolar chromophores based on tetrafluorobenzene (en)
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  • Spectral, electrochemical and calculated properties of quadrupolar chromophores based on tetrafluorobenzene
  • Spectral, electrochemical and calculated properties of quadrupolar chromophores based on tetrafluorobenzene (en)
skos:notation
  • RIV/00216275:25310/14:39897831!RIV15-MSM-25310___
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(EE2.3.30.0021)
http://linked.open...iv/cisloPeriodika
  • září 2014
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
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  • 46561
http://linked.open...ai/riv/idVysledku
  • RIV/00216275:25310/14:39897831
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  • quadrupolar chromophores based on tetrafluorobenzene; electrochemical properties; Spectral properties (en)
http://linked.open.../riv/klicoveSlovo
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  • CZ - Česká republika
http://linked.open...ontrolniKodProRIV
  • [0F3758130E4D]
http://linked.open...i/riv/nazevZdroje
  • Scientific Papers of the University of Pardubice, Series A, Faculty of Chemical Technology
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http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 20
http://linked.open...iv/tvurceVysledku
  • Bureš, Filip
  • Kulhánek, Jiří
  • Vytřas, Karel
  • Mikysek, Tomáš
  • Pytela, Oldřich
  • Almonasy, Numan
  • Ramaiyan, Manikannan
  • Pippig, Falko
issn
  • 1211-5541
number of pages
http://localhost/t...ganizacniJednotka
  • 25310
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