About: Antimony nanoparticle-multiwalled carbon nanotubes composite immobilized at carbon paste electrode for determination of trace heavy metals     Goto   Sponge   NotDistinct   Permalink

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Description
  • A nanocomposite based on multiwalled carbon nanotubes (MWCNT) modified with antimony nanopartides (SbNPs) was synthesized chemically and has been applied to construct an electrode using carbon paste as substrate (SbNP-MWCNT). The developed electrode was applied for the determination of trace heavy metals Pb2+ and Cd2+ by square-wave adsorptive stripping voltammetry. The results were compared with those obtained by related electrode configurations such as Sb-film carbon paste electrode (SbF) and Sb-microsphere-multiwalled carbon nanotube composite carbon paste electrode (Sb-microsphere-MWCNT) in model solutions. The analytical signals for Pb2+ and Cd2+ decreased in the order Isb-nanoparticle } ISb-film } ISb-microsphere indicating that the size of the Sb particles on the coating layer influenced the oxidation current signals of Pb and Cd. The detection limits of the analytes were 0.77 mu g L-1 and 0.65 mu g L-1 for Cd2+ and Pb2+, respectively. The designed electrode was tested for the determination of target ions in wheat flour certified reference material, and the results compared well with those obtained by inductively coupled plasma time-of-flight mass spectrometry, showing satisfactory performance of the composite electrode.
  • A nanocomposite based on multiwalled carbon nanotubes (MWCNT) modified with antimony nanopartides (SbNPs) was synthesized chemically and has been applied to construct an electrode using carbon paste as substrate (SbNP-MWCNT). The developed electrode was applied for the determination of trace heavy metals Pb2+ and Cd2+ by square-wave adsorptive stripping voltammetry. The results were compared with those obtained by related electrode configurations such as Sb-film carbon paste electrode (SbF) and Sb-microsphere-multiwalled carbon nanotube composite carbon paste electrode (Sb-microsphere-MWCNT) in model solutions. The analytical signals for Pb2+ and Cd2+ decreased in the order Isb-nanoparticle } ISb-film } ISb-microsphere indicating that the size of the Sb particles on the coating layer influenced the oxidation current signals of Pb and Cd. The detection limits of the analytes were 0.77 mu g L-1 and 0.65 mu g L-1 for Cd2+ and Pb2+, respectively. The designed electrode was tested for the determination of target ions in wheat flour certified reference material, and the results compared well with those obtained by inductively coupled plasma time-of-flight mass spectrometry, showing satisfactory performance of the composite electrode. (en)
Title
  • Antimony nanoparticle-multiwalled carbon nanotubes composite immobilized at carbon paste electrode for determination of trace heavy metals
  • Antimony nanoparticle-multiwalled carbon nanotubes composite immobilized at carbon paste electrode for determination of trace heavy metals (en)
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  • Antimony nanoparticle-multiwalled carbon nanotubes composite immobilized at carbon paste electrode for determination of trace heavy metals
  • Antimony nanoparticle-multiwalled carbon nanotubes composite immobilized at carbon paste electrode for determination of trace heavy metals (en)
skos:notation
  • RIV/00216275:25310/14:39896539!RIV15-MSM-25310___
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • I
http://linked.open...iv/cisloPeriodika
  • 1
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http://linked.open...aciTvurceVysledku
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  • 3458
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  • RIV/00216275:25310/14:39896539
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  • Wheat flour; Lead and cadmium ions; Nanotube composite; Sb nanoparticles multiwalled carbon; Anodic stripping voltammetry (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • CH - Švýcarská konfederace
http://linked.open...ontrolniKodProRIV
  • [1B83276D0A9D]
http://linked.open...i/riv/nazevZdroje
  • Sensors and Actuators, B: Chemical
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
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http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 191
http://linked.open...iv/tvurceVysledku
  • Husáková, Lenka
  • Urbanová, Iva
  • Vytřas, Karel
  • Ashrafi, Amirmansoor
  • Cerovac, Sandra
  • Guzsvany, Valeria
  • Mudric, Sanja
http://linked.open...ain/vavai/riv/wos
  • 000327771500045
issn
  • 0925-4005
number of pages
http://bibframe.org/vocab/doi
  • 10.1016/j.snb.2013.08.087
http://localhost/t...ganizacniJednotka
  • 25310
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