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  • In this chapter, graphite in powdered form is presented as the material of choice for the preparation and use of the so-called carbon paste electrodes (CPEs). Starting with a short historical reminiscence, when highlighting also the importance of carbon materials in electrochemistry as such, powdered graphite is presented as particularly suitable material for an endless variety of electrodes, sensors, and detectors. Special attention is paid to the graphite powder with respect to its applicability in carbon paste mixtures and, subsequently, in the configuration of CPEs. In this respect, classification of traditional types of graphite powders is also given, completed with a survey of related and/or alternate carbonaceous materials whose applicability to the preparation of CPEs has undergone a real boom in the new millennium and, in fact, resulted in a new renaissance of the field. Furthermore, graphite powders are discussed via physical, physicochemical, and principal electrochemical properties and of similar interest are also the corresponding graphite/carbon paste mixtures, including the experimental know-how on their laboratory preparation and way(s) of housing in specially designed holders and similar assemblies. At the end of this section, one special example is included, summarizing for the first time the recently performed studies on less well-known phenomena within the electrochemistry with CPEs ? the ohmic resistance of carbon pastes in relation with their structure and behavior. Last but not least, the electrochemistry and electroanalysis with CPEs are briefly surveyed, documenting the versatility of these electrodes in modern instrumental analysis, their adaptability to the present day?s trends, as well as great potential in the future, regardless whether one considers traditional graphite powder-based configurations or mixtures from new alternate materials.
  • In this chapter, graphite in powdered form is presented as the material of choice for the preparation and use of the so-called carbon paste electrodes (CPEs). Starting with a short historical reminiscence, when highlighting also the importance of carbon materials in electrochemistry as such, powdered graphite is presented as particularly suitable material for an endless variety of electrodes, sensors, and detectors. Special attention is paid to the graphite powder with respect to its applicability in carbon paste mixtures and, subsequently, in the configuration of CPEs. In this respect, classification of traditional types of graphite powders is also given, completed with a survey of related and/or alternate carbonaceous materials whose applicability to the preparation of CPEs has undergone a real boom in the new millennium and, in fact, resulted in a new renaissance of the field. Furthermore, graphite powders are discussed via physical, physicochemical, and principal electrochemical properties and of similar interest are also the corresponding graphite/carbon paste mixtures, including the experimental know-how on their laboratory preparation and way(s) of housing in specially designed holders and similar assemblies. At the end of this section, one special example is included, summarizing for the first time the recently performed studies on less well-known phenomena within the electrochemistry with CPEs ? the ohmic resistance of carbon pastes in relation with their structure and behavior. Last but not least, the electrochemistry and electroanalysis with CPEs are briefly surveyed, documenting the versatility of these electrodes in modern instrumental analysis, their adaptability to the present day?s trends, as well as great potential in the future, regardless whether one considers traditional graphite powder-based configurations or mixtures from new alternate materials. (en)
Title
  • Graphite Powder and Related Material as the Principal Component of Carbon Paste Electrodes
  • Graphite Powder and Related Material as the Principal Component of Carbon Paste Electrodes (en)
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  • Graphite Powder and Related Material as the Principal Component of Carbon Paste Electrodes
  • Graphite Powder and Related Material as the Principal Component of Carbon Paste Electrodes (en)
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  • RIV/00216275:25310/13:39897110!RIV14-MSM-25310___
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  • I, P(EE2.3.30.0021)
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  • RIV/00216275:25310/13:39897110
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  • review; applications in electroanalysis; physicochemical and electrochemical characterisation; carbon paste electrodes; new carbons; form of carbon; Graphite (en)
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  • [3404F96071D4]
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  • Hauppauge
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  • Graphite: Properties, Occurence and Use
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  • Stočes, Matěj
  • Švancara, Ivan
  • Ludvík, Jiří
  • Mikysek, Tomáš
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  • Nova Science Publishers
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  • 978-1-62618-577-7
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  • 25310
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