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  • Recent achievements in the chemistry of selected group 13 ? 15 elements con-taining pincer type coordinating ligands are summarized. This chapter covers chemistry of heavier elements Ga, In Tl form the group 13, Ge, Sn, Pb ? especially low valent compounds with formal oxidation state +II or +I and their reactivity from the group 14 and As, Sb, Bi from the group 15. Only the classical pincer type ligands containing nitrogen or oxygen atoms as in-built donor functionalities are considered i.e. 2,6-(R2NCH2)2C6H3 (LN1), 2,6-(ArN=C(CH3))2C6H3 (LN2), 2,6-(ROCH2)C6H3 (LO1, 2, R = Me, t-Bu), 2-(Me2NCH2)-6-(ROCH2)C6H3 (LNO1,2, R = Me, t-Bu), 2,6-((RO)2P(O))2-4-(t-Bu)C6H3 (LPO). The influence of the present pincer ligands on the structures of the compounds as well as their key role in the stabilization of these compounds is discussed.
  • Recent achievements in the chemistry of selected group 13 ? 15 elements con-taining pincer type coordinating ligands are summarized. This chapter covers chemistry of heavier elements Ga, In Tl form the group 13, Ge, Sn, Pb ? especially low valent compounds with formal oxidation state +II or +I and their reactivity from the group 14 and As, Sb, Bi from the group 15. Only the classical pincer type ligands containing nitrogen or oxygen atoms as in-built donor functionalities are considered i.e. 2,6-(R2NCH2)2C6H3 (LN1), 2,6-(ArN=C(CH3))2C6H3 (LN2), 2,6-(ROCH2)C6H3 (LO1, 2, R = Me, t-Bu), 2-(Me2NCH2)-6-(ROCH2)C6H3 (LNO1,2, R = Me, t-Bu), 2,6-((RO)2P(O))2-4-(t-Bu)C6H3 (LPO). The influence of the present pincer ligands on the structures of the compounds as well as their key role in the stabilization of these compounds is discussed. (en)
Title
  • The chemistry of pincer complexes of 13 - 15 main group elements
  • The chemistry of pincer complexes of 13 - 15 main group elements (en)
skos:prefLabel
  • The chemistry of pincer complexes of 13 - 15 main group elements
  • The chemistry of pincer complexes of 13 - 15 main group elements (en)
skos:notation
  • RIV/00216275:25310/13:39896814!RIV14-GA0-25310___
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • I, P(GAP207/10/0130)
http://linked.open...iv/cisloPeriodika
  • 2013
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 65246
http://linked.open...ai/riv/idVysledku
  • RIV/00216275:25310/13:39896814
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • 13-15 Main Group Elements; Pincer Complexes; Organometallic (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • DE - Spolková republika Německo
http://linked.open...ontrolniKodProRIV
  • [239684971678]
http://linked.open...i/riv/nazevZdroje
  • Topics in Organometallic Chemistry
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 40
http://linked.open...iv/tvurceVysledku
  • Dostál, Libor
  • Jambor, Roman
http://linked.open...ain/vavai/riv/wos
  • 000312747200006
issn
  • 1436-6002
number of pages
http://bibframe.org/vocab/doi
  • 10.1007/978-3-642-31081-2
http://localhost/t...ganizacniJednotka
  • 25310
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