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  • The synthesis of N -} M intramolecularly coordinated group 14 and 15 chalcogenites is reported. The N -} Sn intramolecularly coordinated organotin(IV) carbonate L(Ph)SnCO3 (1), where L is the N,C,N-chelating ligand 2,6-(Me2NCH2)(2)C6H3-, reacts with SO2 and SeO2 to provide the organotin(IV) sulfite L(Ph)SnSO3 (4) and selenite [L(Ph)SnSeO3](2) (5), respectively. Treatment of [LSbO](2) (2) and [LBiO](2) (3) with SeO2 provided the organoantimony and bismuth selenites LSbSeO3 (6) and [LBiSeO3](3) (7), respectively. Compounds 5-7 are rare examples of mixed element oxides with well-defined stoichiometry MSeO3 (M = Sn, Sb, Bi). Compounds 4-7 were characterized by means of elemental analyses, H-1, C-13, Se-77, and Sn-119 NMR spectroscopies, IR spectroscopy, and single-crystal X-ray diffraction analysis.
  • The synthesis of N -} M intramolecularly coordinated group 14 and 15 chalcogenites is reported. The N -} Sn intramolecularly coordinated organotin(IV) carbonate L(Ph)SnCO3 (1), where L is the N,C,N-chelating ligand 2,6-(Me2NCH2)(2)C6H3-, reacts with SO2 and SeO2 to provide the organotin(IV) sulfite L(Ph)SnSO3 (4) and selenite [L(Ph)SnSeO3](2) (5), respectively. Treatment of [LSbO](2) (2) and [LBiO](2) (3) with SeO2 provided the organoantimony and bismuth selenites LSbSeO3 (6) and [LBiSeO3](3) (7), respectively. Compounds 5-7 are rare examples of mixed element oxides with well-defined stoichiometry MSeO3 (M = Sn, Sb, Bi). Compounds 4-7 were characterized by means of elemental analyses, H-1, C-13, Se-77, and Sn-119 NMR spectroscopies, IR spectroscopy, and single-crystal X-ray diffraction analysis. (en)
Title
  • Intramolecularly Coordinated Group 14 and 15 Chalcogenites
  • Intramolecularly Coordinated Group 14 and 15 Chalcogenites (en)
skos:prefLabel
  • Intramolecularly Coordinated Group 14 and 15 Chalcogenites
  • Intramolecularly Coordinated Group 14 and 15 Chalcogenites (en)
skos:notation
  • RIV/00216275:25310/13:39896783!RIV14-GA0-25310___
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • I, P(GAP106/10/0443), S
http://linked.open...iv/cisloPeriodika
  • 1
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
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  • 80950
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  • RIV/00216275:25310/13:39896783
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  • 3-dimensional structures; organoantimony(iii) oxide; structural-characterization; mixed-oxide; crystal-structures; oxide thin-films; bond covalent radii; fullerene-rich nanostructures; selenite-carboxylate compounds; organic-inorganic nanocomposites (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • US - Spojené státy americké
http://linked.open...ontrolniKodProRIV
  • [52867D21162C]
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  • Organometallics
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  • 32
http://linked.open...iv/tvurceVysledku
  • Dostál, Libor
  • Erben, Milan
  • Jambor, Roman
  • Růžička, Aleš
  • Svoboda, Tomáš
  • Mairychová, Barbora
http://linked.open...ain/vavai/riv/wos
  • 000313606200019
issn
  • 0276-7333
number of pages
http://bibframe.org/vocab/doi
  • 10.1021/om3009553
http://localhost/t...ganizacniJednotka
  • 25310
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