| Attributes | Values |
|---|
| rdf:type
| |
| Description
| - The reaction between in situ prepared THF solution of N,C,N-chelated organobismuth(I) [LBi](n) compound (not isolated), via reaction of LBiCl2 (1) (where L [o,o-C6H3(CH2NMe2)(2)]) with K[B(s-Bu)(3)H] (K-Selectride), and a set of diorganodisulfides ArSSAr gave organobismuth(III) compounds LBi(SAr)(2) 2-7 (where Ar = 2-pyridyl (2), 4-metylthiazol-2-yl (3), thiofen-2-yl (4), 4-tert-butyl-1-iso-propyl-1H-imidazol-2-yl (5), 1-phenyl-1H-tetrazol-5-yl (6), 2-aminophenyl (7)). Compounds 2-7 were characterized by the help of elemental analysis, H-1 and C-13 NMR spectroscopy and in the case of 2, 3 and 6 by the help of single-crystal X-ray diffraction analysis. Compound 7 was unstable in solution and decomposed to compound LBi[S(NH)C6H4] (8), containing five-membered BiSNC2 ring, and the 2-aminothiophenol. Attempts to selectively cleave the Bi-N bond involved in this ring by an acid (such as HCl or acetic acid) failed and led only to the isolation of 1 or acetate LBi(Ac)(2) and elimination of 2-aminothiophenol. Finally, the coordination capability of compound 2 toward both main group (SbCl3, BiCl3, GeCl2 and SnCl2) and transition metal (PdCl2 and PtCl2) compounds was studied.
- The reaction between in situ prepared THF solution of N,C,N-chelated organobismuth(I) [LBi](n) compound (not isolated), via reaction of LBiCl2 (1) (where L [o,o-C6H3(CH2NMe2)(2)]) with K[B(s-Bu)(3)H] (K-Selectride), and a set of diorganodisulfides ArSSAr gave organobismuth(III) compounds LBi(SAr)(2) 2-7 (where Ar = 2-pyridyl (2), 4-metylthiazol-2-yl (3), thiofen-2-yl (4), 4-tert-butyl-1-iso-propyl-1H-imidazol-2-yl (5), 1-phenyl-1H-tetrazol-5-yl (6), 2-aminophenyl (7)). Compounds 2-7 were characterized by the help of elemental analysis, H-1 and C-13 NMR spectroscopy and in the case of 2, 3 and 6 by the help of single-crystal X-ray diffraction analysis. Compound 7 was unstable in solution and decomposed to compound LBi[S(NH)C6H4] (8), containing five-membered BiSNC2 ring, and the 2-aminothiophenol. Attempts to selectively cleave the Bi-N bond involved in this ring by an acid (such as HCl or acetic acid) failed and led only to the isolation of 1 or acetate LBi(Ac)(2) and elimination of 2-aminothiophenol. Finally, the coordination capability of compound 2 toward both main group (SbCl3, BiCl3, GeCl2 and SnCl2) and transition metal (PdCl2 and PtCl2) compounds was studied. (en)
|
| Title
| - Oxidative addition of organic disulfides to low valent N,C,N-chelated organobismuth(I) compound: Isolation, structure and coordination capability of substituted bismuth(III) bis(arylsulfides)
- Oxidative addition of organic disulfides to low valent N,C,N-chelated organobismuth(I) compound: Isolation, structure and coordination capability of substituted bismuth(III) bis(arylsulfides) (en)
|
| skos:prefLabel
| - Oxidative addition of organic disulfides to low valent N,C,N-chelated organobismuth(I) compound: Isolation, structure and coordination capability of substituted bismuth(III) bis(arylsulfides)
- Oxidative addition of organic disulfides to low valent N,C,N-chelated organobismuth(I) compound: Isolation, structure and coordination capability of substituted bismuth(III) bis(arylsulfides) (en)
|
| skos:notation
| - RIV/00216275:25310/13:39896779!RIV14-GA0-25310___
|
| http://linked.open...avai/riv/aktivita
| |
| http://linked.open...avai/riv/aktivity
| |
| http://linked.open...iv/cisloPeriodika
| |
| http://linked.open...vai/riv/dodaniDat
| |
| http://linked.open...aciTvurceVysledku
| |
| http://linked.open.../riv/druhVysledku
| |
| http://linked.open...iv/duvernostUdaju
| |
| http://linked.open...titaPredkladatele
| |
| http://linked.open...dnocenehoVysledku
| |
| http://linked.open...ai/riv/idVysledku
| - RIV/00216275:25310/13:39896779
|
| http://linked.open...riv/jazykVysledku
| |
| http://linked.open.../riv/klicovaSlova
| - NMR; X-ray structures; chelating ligands; oxidative addition; bismuth (en)
|
| http://linked.open.../riv/klicoveSlovo
| |
| http://linked.open...odStatuVydavatele
| - CH - Švýcarská konfederace
|
| http://linked.open...ontrolniKodProRIV
| |
| http://linked.open...i/riv/nazevZdroje
| - Journal of Organometallic Chemistry
|
| http://linked.open...in/vavai/riv/obor
| |
| http://linked.open...ichTvurcuVysledku
| |
| http://linked.open...cetTvurcuVysledku
| |
| http://linked.open...vavai/riv/projekt
| |
| http://linked.open...UplatneniVysledku
| |
| http://linked.open...v/svazekPeriodika
| |
| http://linked.open...iv/tvurceVysledku
| - Dostál, Libor
- Jambor, Roman
- Růžička, Aleš
- Šimon, Petr
|
| http://linked.open...ain/vavai/riv/wos
| |
| issn
| |
| number of pages
| |
| http://bibframe.org/vocab/doi
| - 10.1016/j.jorganchem.2013.05.005
|
| http://localhost/t...ganizacniJednotka
| |
![[RDF Data]](/fct/images/sw-rdf-blue.png)
![[cxml]](/fct/images/cxml_doc.png)
![[csv]](/fct/images/csv_doc.png)
![[text]](/fct/images/ntriples_doc.png)
![[turtle]](/fct/images/n3turtle_doc.png)
![[ld+json]](/fct/images/jsonld_doc.png)
![[rdf+json]](/fct/images/json_doc.png)
![[rdf+xml]](/fct/images/xml_doc.png)
![[atom+xml]](/fct/images/atom_doc.png)
![[html]](/fct/images/html_doc.png)