| Attributes | Values |
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| rdf:type
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| Description
| - The reaction of N,C-intramolecularly coordinated organoantimony(III) compound L2SbCl (1) (where L is [2-(2',6'-i-Pr2C6H3)N=CHC6H4]) with one molar equivalent of the K-selectride (K[B(s-Bu)(3)H]) gave compound LSb{2-[CH2N(2',6'-i-Pr2C6H3)]C6H4} (2) containing five membered aza-stiba heterocycle. On the contrary, analogical reaction between the organobismuth(III) compound L2BiCl (3) and K-selectride gave only inseparable mixture of products. Reactions of 2 with selected acids HX resulted in the cleavage of the present Sb-N bond and formation of novel N, C-chelated compounds LSb(X){2-[CH2NH(2',6'-i-Pr2C6H3)]C6H4} (where X = Cl (4), CH3COO (5), CF3COO (6), CF3SO3 (7) or FcCOO (8); Fc = ferrocenyl). Compounds 4-8 were characterized by the help of elemental analysis, electrospray ionization (ESI) mass spectrometry, multinuclear NMR spectroscopy, IR spectroscopy and in the case of 5 by the single-crystal X-ray diffraction analysis. The molecular structures of compounds LSb(X){2-[CH2NH(2',6'-i-Pr2C6H3)]C6H4}center dot HX (where X = CF3COO (6a), CF3SO3 (7a)) were determined by the single-crystal X-ray diffraction analysis as well. Compounds 6a and 7a are most probably products of partial hydrolysis of compounds 6 and 7.
- The reaction of N,C-intramolecularly coordinated organoantimony(III) compound L2SbCl (1) (where L is [2-(2',6'-i-Pr2C6H3)N=CHC6H4]) with one molar equivalent of the K-selectride (K[B(s-Bu)(3)H]) gave compound LSb{2-[CH2N(2',6'-i-Pr2C6H3)]C6H4} (2) containing five membered aza-stiba heterocycle. On the contrary, analogical reaction between the organobismuth(III) compound L2BiCl (3) and K-selectride gave only inseparable mixture of products. Reactions of 2 with selected acids HX resulted in the cleavage of the present Sb-N bond and formation of novel N, C-chelated compounds LSb(X){2-[CH2NH(2',6'-i-Pr2C6H3)]C6H4} (where X = Cl (4), CH3COO (5), CF3COO (6), CF3SO3 (7) or FcCOO (8); Fc = ferrocenyl). Compounds 4-8 were characterized by the help of elemental analysis, electrospray ionization (ESI) mass spectrometry, multinuclear NMR spectroscopy, IR spectroscopy and in the case of 5 by the single-crystal X-ray diffraction analysis. The molecular structures of compounds LSb(X){2-[CH2NH(2',6'-i-Pr2C6H3)]C6H4}center dot HX (where X = CF3COO (6a), CF3SO3 (7a)) were determined by the single-crystal X-ray diffraction analysis as well. Compounds 6a and 7a are most probably products of partial hydrolysis of compounds 6 and 7. (en)
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| Title
| - Opening of the azastibol heterocycle with various acids: Isolation of novel N,C-chelated organoantimony(III) compounds
- Opening of the azastibol heterocycle with various acids: Isolation of novel N,C-chelated organoantimony(III) compounds (en)
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| skos:prefLabel
| - Opening of the azastibol heterocycle with various acids: Isolation of novel N,C-chelated organoantimony(III) compounds
- Opening of the azastibol heterocycle with various acids: Isolation of novel N,C-chelated organoantimony(III) compounds (en)
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| skos:notation
| - RIV/00216275:25310/13:39896778!RIV14-MSM-25310___
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| http://linked.open...avai/riv/aktivita
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| http://linked.open...avai/riv/aktivity
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| http://linked.open...iv/cisloPeriodika
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| http://linked.open...vai/riv/dodaniDat
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| http://linked.open...aciTvurceVysledku
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| http://linked.open.../riv/druhVysledku
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| http://linked.open...iv/duvernostUdaju
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| http://linked.open...titaPredkladatele
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| http://linked.open...dnocenehoVysledku
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| http://linked.open...ai/riv/idVysledku
| - RIV/00216275:25310/13:39896778
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| http://linked.open...riv/jazykVysledku
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| http://linked.open.../riv/klicovaSlova
| - NMR; X-ray structures; chelating ligands; azastiboles; antimony (en)
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| http://linked.open.../riv/klicoveSlovo
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| http://linked.open...odStatuVydavatele
| - CH - Švýcarská konfederace
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| http://linked.open...ontrolniKodProRIV
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| http://linked.open...i/riv/nazevZdroje
| - Journal of Organometallic Chemistry
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| http://linked.open...in/vavai/riv/obor
| |
| http://linked.open...ichTvurcuVysledku
| |
| http://linked.open...cetTvurcuVysledku
| |
| http://linked.open...UplatneniVysledku
| |
| http://linked.open...v/svazekPeriodika
| |
| http://linked.open...iv/tvurceVysledku
| - Dostál, Libor
- Erben, Milan
- Jambor, Roman
- Růžička, Aleš
- Jirásko, Robert
- Vránová, Iva
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| http://linked.open...ain/vavai/riv/wos
| |
| issn
| |
| number of pages
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| http://bibframe.org/vocab/doi
| - 10.1016/j.jorganchem.2013.06.023
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| http://localhost/t...ganizacniJednotka
| |
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