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Description
| - The temperature dependence of viscosity of three compositional series of PbO-WO3-P2O5 glasses with compositions (0.5-x/2) PbO center dot xWO(3)center dot(0.5-x/2)P2O5, x=0, 0.1, 0.2, 0.3, 0.4, 0.5, 0.6; 0.5PbO center dot xWO(3)center dot(0.5-x)P2O5, x=0.1, 0.2, 0.3; and (0.5-x)PbO. xWO(3)center dot 0.5P(2)O(5), x=0.1, 0.2, 0.3, 04 measured by thermomechanical analysis is reported. The Andrade viscosity equation was successfully used to describe the temperature dependence of viscosity and to evaluate of the temperature independent activation energy for viscous flow. The results are discussed in terms of the glass structure by considering the network forming/modifying function of individual oxides. A simplified structural model is proposed and verified by a multilinear regression analysis of the compositional dependence of the activation energy for viscous flow and the glass transition temperature.
- The temperature dependence of viscosity of three compositional series of PbO-WO3-P2O5 glasses with compositions (0.5-x/2) PbO center dot xWO(3)center dot(0.5-x/2)P2O5, x=0, 0.1, 0.2, 0.3, 0.4, 0.5, 0.6; 0.5PbO center dot xWO(3)center dot(0.5-x)P2O5, x=0.1, 0.2, 0.3; and (0.5-x)PbO. xWO(3)center dot 0.5P(2)O(5), x=0.1, 0.2, 0.3, 04 measured by thermomechanical analysis is reported. The Andrade viscosity equation was successfully used to describe the temperature dependence of viscosity and to evaluate of the temperature independent activation energy for viscous flow. The results are discussed in terms of the glass structure by considering the network forming/modifying function of individual oxides. A simplified structural model is proposed and verified by a multilinear regression analysis of the compositional dependence of the activation energy for viscous flow and the glass transition temperature. (en)
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Title
| - Viscosity and activation energy for viscous flow of PbO-WO3-P2O5 glasses
- Viscosity and activation energy for viscous flow of PbO-WO3-P2O5 glasses (en)
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skos:prefLabel
| - Viscosity and activation energy for viscous flow of PbO-WO3-P2O5 glasses
- Viscosity and activation energy for viscous flow of PbO-WO3-P2O5 glasses (en)
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skos:notation
| - RIV/00216275:25310/13:39896465!RIV14-GA0-25310___
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http://linked.open...avai/riv/aktivita
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http://linked.open...avai/riv/aktivity
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http://linked.open...iv/cisloPeriodika
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http://linked.open...vai/riv/dodaniDat
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http://linked.open...aciTvurceVysledku
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http://linked.open.../riv/druhVysledku
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http://linked.open...iv/duvernostUdaju
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http://linked.open...titaPredkladatele
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http://linked.open...dnocenehoVysledku
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http://linked.open...ai/riv/idVysledku
| - RIV/00216275:25310/13:39896465
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http://linked.open...riv/jazykVysledku
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http://linked.open.../riv/klicovaSlova
| - activation energy; viscous flow; viscosity; phosphate glasses (en)
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http://linked.open.../riv/klicoveSlovo
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http://linked.open...odStatuVydavatele
| - GB - Spojené království Velké Británie a Severního Irska
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http://linked.open...ontrolniKodProRIV
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http://linked.open...i/riv/nazevZdroje
| - Physics and Chemistry of Glasses: European Journal of Glass Science and Technology Part B
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http://linked.open...in/vavai/riv/obor
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http://linked.open...ichTvurcuVysledku
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http://linked.open...cetTvurcuVysledku
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http://linked.open...vavai/riv/projekt
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http://linked.open...UplatneniVysledku
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http://linked.open...v/svazekPeriodika
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http://linked.open...iv/tvurceVysledku
| - Liška, Marek
- Chromčíková, Mária
- Koudelka, Ladislav
- Mošner, Petr
- Rösslerová, Ivana
- Lissová, Magdaléna
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http://linked.open...ain/vavai/riv/wos
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issn
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number of pages
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http://localhost/t...ganizacniJednotka
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