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Description
  • This study deals with rutile pigments of type Ti1-3xCrxM2xO2 (where M = Sb, W and x = 0, 0.05, 0.10, 0.20, 0.30, 0.50) prepared by solid state reaction. Chromium is the chromophore (coloring ion); antimony and tungsten are added for achieving electroneutrality. The effect of doping elements (M = Sb, W), calcination temperature (850, 950, 1050, 1150 degrees C) and composition (x = 0, 0.05, 0.10, 0.20, 0.30, 0.50) on color properties, particle size and electrokinetic (zeta) potential was observed. The optimal conditions for synthesis of these rutile pigments are Sb2O3 as raw material, calcination temperature 1050 degrees C and composition x = 0.20 (Ti0.4Cr0.2Sb0.4O2). This orange-green pigment has high stable dispersion (zeta = -43.81 mV) and good color properties (chroma C = 39.50). However, brightly orange pigment Ti0.85Cr0.05W0.10O2 (x = 0.05) synthesized at temperature 1050 degrees C gives %22the finest%22 color with higher chroma (C = 49.48), but less stable dispersion (zeta = -37.32 mV). In light of phase composition, the optimal calcination temperature is 1150 degrees C.
  • This study deals with rutile pigments of type Ti1-3xCrxM2xO2 (where M = Sb, W and x = 0, 0.05, 0.10, 0.20, 0.30, 0.50) prepared by solid state reaction. Chromium is the chromophore (coloring ion); antimony and tungsten are added for achieving electroneutrality. The effect of doping elements (M = Sb, W), calcination temperature (850, 950, 1050, 1150 degrees C) and composition (x = 0, 0.05, 0.10, 0.20, 0.30, 0.50) on color properties, particle size and electrokinetic (zeta) potential was observed. The optimal conditions for synthesis of these rutile pigments are Sb2O3 as raw material, calcination temperature 1050 degrees C and composition x = 0.20 (Ti0.4Cr0.2Sb0.4O2). This orange-green pigment has high stable dispersion (zeta = -43.81 mV) and good color properties (chroma C = 39.50). However, brightly orange pigment Ti0.85Cr0.05W0.10O2 (x = 0.05) synthesized at temperature 1050 degrees C gives %22the finest%22 color with higher chroma (C = 49.48), but less stable dispersion (zeta = -37.32 mV). In light of phase composition, the optimal calcination temperature is 1150 degrees C. (en)
Title
  • The Study of Rutile Pigments Ti1-3xCrxM2xO2
  • The Study of Rutile Pigments Ti1-3xCrxM2xO2 (en)
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  • The Study of Rutile Pigments Ti1-3xCrxM2xO2
  • The Study of Rutile Pigments Ti1-3xCrxM2xO2 (en)
skos:notation
  • RIV/00216275:25310/13:39896414!RIV14-MSM-25310___
http://linked.open...avai/riv/aktivita
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  • I, S
http://linked.open...iv/cisloPeriodika
  • 9
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  • 108750
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  • RIV/00216275:25310/13:39896414
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  • X-ray Powder Diffraction; Electrokinetic (zeta) Potential; Particle Size Distribution; Color Properties; Rutile Pigments (en)
http://linked.open.../riv/klicoveSlovo
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  • PL - Polská republika
http://linked.open...ontrolniKodProRIV
  • [0ED85B6FB2FE]
http://linked.open...i/riv/nazevZdroje
  • Central European Journal of Chemistry
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  • 11
http://linked.open...iv/tvurceVysledku
  • Mikulášek, Petr
  • Čech, Jan
  • Šulcová, Petra
  • Večeřa, Jan
http://linked.open...ain/vavai/riv/wos
  • 000321068300006
issn
  • 1895-1066
number of pages
http://bibframe.org/vocab/doi
  • 10.2478/s11532-013-0287-3
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  • 25310
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