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  • The origin of a power-law correlation between ionic conductivity and cation-contents, found commonly in oxide and chalcogenide glasses, is discussed using the concept of configuration entropy. It is suggested that power-law dependence is primarily attributed to an increase in configuration entropy with mixing cation components into glasses. This effect reduces the potential barrier height to be surmounted by mobile ions, which results in a higher diffusion coefficient (and hence conductivity). The origin of anomalous pre-exponential factors of diffusion coefficient and conductivity can be interpreted in terms of the present context. (C) 2013 American Institute of Physics. [http://dx.doi.org/10.1063/1.4798595]
  • The origin of a power-law correlation between ionic conductivity and cation-contents, found commonly in oxide and chalcogenide glasses, is discussed using the concept of configuration entropy. It is suggested that power-law dependence is primarily attributed to an increase in configuration entropy with mixing cation components into glasses. This effect reduces the potential barrier height to be surmounted by mobile ions, which results in a higher diffusion coefficient (and hence conductivity). The origin of anomalous pre-exponential factors of diffusion coefficient and conductivity can be interpreted in terms of the present context. (C) 2013 American Institute of Physics. [http://dx.doi.org/10.1063/1.4798595] (en)
Title
  • Origin of power-law composition dependence in ionic transport glasses
  • Origin of power-law composition dependence in ionic transport glasses (en)
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  • Origin of power-law composition dependence in ionic transport glasses
  • Origin of power-law composition dependence in ionic transport glasses (en)
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  • RIV/00216275:25310/13:39896396!RIV14-MSM-25310___
http://linked.open...avai/riv/aktivita
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  • P(EE2.3.20.0254)
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  • 14
http://linked.open...vai/riv/dodaniDat
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  • 94644
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  • RIV/00216275:25310/13:39896396
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  • conductivity; configuration entropy; chalcogenide glasses; power-law (en)
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  • US - Spojené státy americké
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  • [D6544DED6392]
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  • Journal of Applied Physics
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http://linked.open...UplatneniVysledku
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  • 113
http://linked.open...iv/tvurceVysledku
  • Wágner, Tomáš
  • Shimakawa, Koichi
http://linked.open...ain/vavai/riv/wos
  • 000318250600032
issn
  • 0021-8979
number of pages
http://bibframe.org/vocab/doi
  • 10.1063/1.4798595
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  • 25310
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