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Description
| - The thermal behavior and decompn. kinetics of Viton A bonded PBXs contg. some attractive cyclic nitramines were investigated by means of nonisothermal TG and DSC techniques. It has been shown that only a single decompn. process has been obsd. for RDX-VA, CL-20-VA and HMX-VA while an obvious two-step process for BCHMX-VA under 1.0° min-1. The exothermic onset temps. of RDX-VA, BCHMX-VA, HMX-VA and CL-20-VA were found as 212.6, 241.3, 277.6, and 237.8° with the peak max. of 234.1, 242.6, 278.7, and 238.6°, resp. Their corresponding heat releases were detd. as 1552, 1263, 1302, and 1597 J g-1, which are much lower than that of the pure cyclic nitramines. It has been proved that Formex polymer is not good binder for BCHMX, while Viton A is better than C4 and Formex as the binder of cyclic nitramines for the sake of greater thermal stability. Viton A has a significant effect on the activation energy distribution of cyclic nitramines, and the initial autocatalysis effect for RDX and BCHMX was weakened or inhibited.
- The thermal behavior and decompn. kinetics of Viton A bonded PBXs contg. some attractive cyclic nitramines were investigated by means of nonisothermal TG and DSC techniques. It has been shown that only a single decompn. process has been obsd. for RDX-VA, CL-20-VA and HMX-VA while an obvious two-step process for BCHMX-VA under 1.0° min-1. The exothermic onset temps. of RDX-VA, BCHMX-VA, HMX-VA and CL-20-VA were found as 212.6, 241.3, 277.6, and 237.8° with the peak max. of 234.1, 242.6, 278.7, and 238.6°, resp. Their corresponding heat releases were detd. as 1552, 1263, 1302, and 1597 J g-1, which are much lower than that of the pure cyclic nitramines. It has been proved that Formex polymer is not good binder for BCHMX, while Viton A is better than C4 and Formex as the binder of cyclic nitramines for the sake of greater thermal stability. Viton A has a significant effect on the activation energy distribution of cyclic nitramines, and the initial autocatalysis effect for RDX and BCHMX was weakened or inhibited. (en)
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Title
| - Thermal behavior and decomposition kinetics of Viton A bonded explosives containing attractive cyclic nitramines
- Thermal behavior and decomposition kinetics of Viton A bonded explosives containing attractive cyclic nitramines (en)
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skos:prefLabel
| - Thermal behavior and decomposition kinetics of Viton A bonded explosives containing attractive cyclic nitramines
- Thermal behavior and decomposition kinetics of Viton A bonded explosives containing attractive cyclic nitramines (en)
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skos:notation
| - RIV/00216275:25310/13:39896351!RIV14-MV0-25310___
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http://linked.open...avai/riv/aktivita
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http://linked.open...avai/riv/aktivity
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http://linked.open...iv/cisloPeriodika
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http://linked.open...vai/riv/dodaniDat
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http://linked.open...aciTvurceVysledku
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http://linked.open.../riv/druhVysledku
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http://linked.open...iv/duvernostUdaju
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http://linked.open...titaPredkladatele
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http://linked.open...dnocenehoVysledku
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http://linked.open...ai/riv/idVysledku
| - RIV/00216275:25310/13:39896351
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http://linked.open...riv/jazykVysledku
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http://linked.open.../riv/klicovaSlova
| - Viton A; activation energy; thermal decomposition; cyclic nitramines; PBX (en)
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http://linked.open.../riv/klicoveSlovo
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http://linked.open...odStatuVydavatele
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http://linked.open...ontrolniKodProRIV
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http://linked.open...i/riv/nazevZdroje
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http://linked.open...in/vavai/riv/obor
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http://linked.open...ichTvurcuVysledku
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http://linked.open...cetTvurcuVysledku
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http://linked.open...vavai/riv/projekt
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http://linked.open...UplatneniVysledku
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http://linked.open...v/svazekPeriodika
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http://linked.open...iv/tvurceVysledku
| - Elbeih, Ahmed Ikhlas Mohamed
- Zeman, Svatopluk
- Yan, Qi Long
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http://linked.open...ain/vavai/riv/wos
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issn
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number of pages
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http://bibframe.org/vocab/doi
| - 10.1016/j.tca.2013.03.041
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http://localhost/t...ganizacniJednotka
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