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Description
  • Reaction of Cp2VCl2 with alpha-amino acids bearing functional group in the side chain gives N,O-chelate complexes [Cp2V(N,O-aa)]Cl (aa = ser, thr, asp, glu, asn, gin, lys, arg). These complexes were studied by spectroscopic methods (EPR, IR and Raman). All prepared complexes contain amino acid ligand bonded via oxygen atom of carboxylic group and nitrogen atom of amino group in alpha-position giving five-membered chelate ring. We have observed that hydroxy, amine, carboxylic, amide and guanidinium groups present in alpha-amino acid ligand are not able to coordinate to the central vanadium atom.
  • Reaction of Cp2VCl2 with alpha-amino acids bearing functional group in the side chain gives N,O-chelate complexes [Cp2V(N,O-aa)]Cl (aa = ser, thr, asp, glu, asn, gin, lys, arg). These complexes were studied by spectroscopic methods (EPR, IR and Raman). All prepared complexes contain amino acid ligand bonded via oxygen atom of carboxylic group and nitrogen atom of amino group in alpha-position giving five-membered chelate ring. We have observed that hydroxy, amine, carboxylic, amide and guanidinium groups present in alpha-amino acid ligand are not able to coordinate to the central vanadium atom. (en)
Title
  • Vanadocene complexes of amino acids bearing functional group in the side chain
  • Vanadocene complexes of amino acids bearing functional group in the side chain (en)
skos:prefLabel
  • Vanadocene complexes of amino acids bearing functional group in the side chain
  • Vanadocene complexes of amino acids bearing functional group in the side chain (en)
skos:notation
  • RIV/00216275:25310/13:39896343!RIV14-MSM-25310___
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • I, S
http://linked.open...iv/cisloPeriodika
  • 11
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 113594
http://linked.open...ai/riv/idVysledku
  • RIV/00216275:25310/13:39896343
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • metallocene; X-ray diffraction; EPR spectroscopy; amino acid; vanadocene dichloride (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • CH - Švýcarská konfederace
http://linked.open...ontrolniKodProRIV
  • [36936E508DEA]
http://linked.open...i/riv/nazevZdroje
  • Inorganica Chimica Acta
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 405
http://linked.open...iv/tvurceVysledku
  • Erben, Milan
  • Růžička, Aleš
  • Vinklárek, Jaromír
  • Eisner, Aleš
  • Honzíček, Jan
  • Honzíčková, Iva
http://linked.open...ain/vavai/riv/wos
  • 000324223200018
issn
  • 0020-1693
number of pages
http://bibframe.org/vocab/doi
  • 10.1016/j.ica.2013.05.020
http://localhost/t...ganizacniJednotka
  • 25310
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