About: Effect of Polar Plasticizers on the Characteristics of Selected Cyclic Nitramines

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
rdfs:seeAlso	http://www.wydawnictwa.ipo.waw.pl/cejem/vol-10-03-2013/Elbeih.pdf
Description	Dioctyl sebacate (DOS) is a part of polyisobutylene binder (PIB) to form a polymeric C4 matrix. PBXs with this matrix were filled by: BCHMX (cis-1,3,4,6-tetranitrooctahydroimidazo [4,5 d]imidazole), ?-HNIW (?-2,4,6,8,10,12-hexanitro-2,4,6,8,10,12-hexaaza-isowurtzitane), RDX (1,3,5-trinitro-1,3,5-triazacyclohexane), and HMX (1,3,5,7-tetranitro-1,3,5,7-tetrazacyclooctane). Similarly Fluorel binder was used in PBXs based on the same selected nitramines. Impact and friction sensitivities of these PBXs and the pure fillers were measured. The thermal stability was studied using DTA. HPLC was used to detect the presence of BCHMX dissolved in DOS. The heat of combustion of the PBXs and of the pure explosive fillers was specified using a bomb calorimetry. PIB softened by DOS has a greater effect on decreasing the impact sensitivity of the studied pure nitramine fillers than Fluorel binder. However, the plasticizer acts as a solvent for the energetic materials and decreases the decompn. temp. of these plastic explosives. Dioctyl sebacate (DOS) is a part of polyisobutylene binder (PIB) to form a polymeric C4 matrix. PBXs with this matrix were filled by: BCHMX (cis-1,3,4,6-tetranitrooctahydroimidazo [4,5 d]imidazole), ?-HNIW (?-2,4,6,8,10,12-hexanitro-2,4,6,8,10,12-hexaaza-isowurtzitane), RDX (1,3,5-trinitro-1,3,5-triazacyclohexane), and HMX (1,3,5,7-tetranitro-1,3,5,7-tetrazacyclooctane). Similarly Fluorel binder was used in PBXs based on the same selected nitramines. Impact and friction sensitivities of these PBXs and the pure fillers were measured. The thermal stability was studied using DTA. HPLC was used to detect the presence of BCHMX dissolved in DOS. The heat of combustion of the PBXs and of the pure explosive fillers was specified using a bomb calorimetry. PIB softened by DOS has a greater effect on decreasing the impact sensitivity of the studied pure nitramine fillers than Fluorel binder. However, the plasticizer acts as a solvent for the energetic materials and decreases the decompn. temp. of these plastic explosives. (en)
Title	Effect of Polar Plasticizers on the Characteristics of Selected Cyclic Nitramines Effect of Polar Plasticizers on the Characteristics of Selected Cyclic Nitramines (en)
skos:prefLabel	Effect of Polar Plasticizers on the Characteristics of Selected Cyclic Nitramines Effect of Polar Plasticizers on the Characteristics of Selected Cyclic Nitramines (en)
skos:notation	RIV/00216275:25310/13:39896301!RIV14-MSM-25310___
http://linked.open...avai/riv/aktivita	I
http://linked.open...avai/riv/aktivity	I
http://linked.open...iv/cisloPeriodika	3
http://linked.open...vai/riv/dodaniDat	2014
http://linked.open...aciTvurceVysledku	Zeman, Svatopluk Pachmáň, Jiří Elbeih, Ahmed Ikhlas Mohamed
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Univerzita Pardubice / Fakulta chemicko-technologická
http://linked.open...dnocenehoVysledku	71673
http://linked.open...ai/riv/idVysledku	RIV/00216275:25310/13:39896301
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	thermal stability; combustion; sensitivity; polymers; energetic materials (en)
http://linked.open.../riv/klicoveSlovo	polymers combustion thermal stability energetic materials sensitivity
http://linked.open...odStatuVydavatele	PL - Polská republika
http://linked.open...ontrolniKodProRIV	[51140840FB78]
http://linked.open...i/riv/nazevZdroje	Central European Journal of Energetic Materials
http://linked.open...in/vavai/riv/obor	JY
http://linked.open...ichTvurcuVysledku	3 (xsd:int)
http://linked.open...cetTvurcuVysledku	3 (xsd:int)
http://linked.open...UplatneniVysledku	2013
http://linked.open...v/svazekPeriodika	10
http://linked.open...iv/tvurceVysledku	Elbeih, Ahmed Ikhlas Mohamed Pachmáň, Jiří Zeman, Svatopluk
http://linked.open...ain/vavai/riv/wos	000325240200004
issn	1733-7178
number of pages	11 (xsd:int)
http://localhost/t...ganizacniJednotka	25310

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