About: Three Isomers of Aryl-Substituted Twelve-Vertex Ferratricarbollides     Goto   Sponge   NotDistinct   Permalink

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Description
  • A series of the first types of monoaryl-substituted 12-vertex ferratricarbollide complexes of general constitution [1-(CpFe)-closo-ArC3B8H10] (where Ar = C6H5, 1'-C10H7, 2'-C10H7) with three different aryl substituents and arrangements of cluster carbon vertexes were isolated from high-temperature reactions between 8-Ar-nido-7,8,9-C3B8H11 compounds and [CpFe(CO)(2)](2). The Fe complexation is accompanied by extensive rearrangement of the cluster carbon atoms over the 12-vertex cage.
  • A series of the first types of monoaryl-substituted 12-vertex ferratricarbollide complexes of general constitution [1-(CpFe)-closo-ArC3B8H10] (where Ar = C6H5, 1'-C10H7, 2'-C10H7) with three different aryl substituents and arrangements of cluster carbon vertexes were isolated from high-temperature reactions between 8-Ar-nido-7,8,9-C3B8H11 compounds and [CpFe(CO)(2)](2). The Fe complexation is accompanied by extensive rearrangement of the cluster carbon atoms over the 12-vertex cage. (en)
Title
  • Three Isomers of Aryl-Substituted Twelve-Vertex Ferratricarbollides
  • Three Isomers of Aryl-Substituted Twelve-Vertex Ferratricarbollides (en)
skos:prefLabel
  • Three Isomers of Aryl-Substituted Twelve-Vertex Ferratricarbollides
  • Three Isomers of Aryl-Substituted Twelve-Vertex Ferratricarbollides (en)
skos:notation
  • RIV/00216275:25310/13:39896292!RIV14-GA0-25310___
http://linked.open...avai/riv/aktivita
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  • I, P(GAP207/11/0705)
http://linked.open...iv/cisloPeriodika
  • 2
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  • 111024
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  • RIV/00216275:25310/13:39896292
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  • mehn; iron; bu(t)hn; derivatives; rearrangement; tricarbaboranes; series; metallatricarbaborane complexes; structural characterizations; tricarbon carborane chemistry (en)
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  • US - Spojené státy americké
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  • [D3AED6469C94]
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  • Organometallics
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  • 32
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  • Bakardjiev, Mario
  • Holub, Josef
  • Padělková, Zdeňka
  • Růžička, Aleš
  • Štíbr, Bohumil
  • Gruener, Bohumír
http://linked.open...ain/vavai/riv/wos
  • 000314332100003
issn
  • 0276-7333
number of pages
http://bibframe.org/vocab/doi
  • 10.1021/om3011118
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  • 25310
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