About: Quest for lithium amidinates containing adjacent amino donor group at the central carbon atom

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About: Quest for lithium amidinates containing adjacent amino donor group at the central carbon atom Goto Sponge NotDistinct Permalink

An Entity of Type : http://linked.opendata.cz/ontology/domain/vavai/Vysledek, within Data Space : linked.opendata.cz associated with source document(s)

Attributes	Values
rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
rdfs:seeAlso	http://www.sciencedirect.com/science/article/pii/S0022328X13005743
Description	Lithium amidinate complexes bearing different peripheral substituents on both nitrogen atoms (iPr and Dipp (2,6-di(isopropyl)phenyl-) and pendant, potentially coordinating group originated from the 2-(N,N-dimethylaminomethyl)phenyl moiety, at the central carbon atom were prepared by addition of the 2(N,N-dimethylaminomethyl)phenyllithium to the appropriate carbodiimides. The structure of the isopropyl group substituted lithium amidinates is dimeric with bidentate amidinate unit and four-coordinated lithium atom. On contrary the Dipp group substituted lithium amidinate is monomeric with trigonal planar geometry of the lithium atom, monodentately bound amidinate unit and coordinated pendant arm. Lithium amidinate complexes bearing different peripheral substituents on both nitrogen atoms (iPr and Dipp (2,6-di(isopropyl)phenyl-) and pendant, potentially coordinating group originated from the 2-(N,N-dimethylaminomethyl)phenyl moiety, at the central carbon atom were prepared by addition of the 2(N,N-dimethylaminomethyl)phenyllithium to the appropriate carbodiimides. The structure of the isopropyl group substituted lithium amidinates is dimeric with bidentate amidinate unit and four-coordinated lithium atom. On contrary the Dipp group substituted lithium amidinate is monomeric with trigonal planar geometry of the lithium atom, monodentately bound amidinate unit and coordinated pendant arm. (en)
Title	Quest for lithium amidinates containing adjacent amino donor group at the central carbon atom Quest for lithium amidinates containing adjacent amino donor group at the central carbon atom (en)
skos:prefLabel	Quest for lithium amidinates containing adjacent amino donor group at the central carbon atom Quest for lithium amidinates containing adjacent amino donor group at the central carbon atom (en)
skos:notation	RIV/00216275:25310/13:39896220!RIV14-GA0-25310___
http://linked.open...avai/riv/aktivita	I P S
http://linked.open...avai/riv/aktivity	I, P(GAP207/12/0223), S
http://linked.open...iv/cisloPeriodika	November
http://linked.open...vai/riv/dodaniDat	2014
http://linked.open...aciTvurceVysledku	Nevoralová, Jana Růžička, Aleš Padělková, Zdeňka Chlupatý, Tomáš
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Univerzita Pardubice / Fakulta chemicko-technologická
http://linked.open...dnocenehoVysledku	101267
http://linked.open...ai/riv/idVysledku	RIV/00216275:25310/13:39896220
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	XRD; NMR; lithium; N-chelate; C; amidinate (en)
http://linked.open.../riv/klicoveSlovo	N-chelate amidinate NMR XRD lithium C
http://linked.open...odStatuVydavatele	CH - Švýcarská konfederace
http://linked.open...ontrolniKodProRIV	[705097023F5E]
http://linked.open...i/riv/nazevZdroje	Journal of Organometallic Chemistry
http://linked.open...in/vavai/riv/obor	CA
http://linked.open...ichTvurcuVysledku	4 (xsd:int)
http://linked.open...cetTvurcuVysledku	4 (xsd:int)
http://linked.open...vavai/riv/projekt	Hybridní ligandy pro stabilizaci/specifickou aktivaci kovových center v nízkých oxidačních stavech.
http://linked.open...UplatneniVysledku	2013
http://linked.open...v/svazekPeriodika	745-746
http://linked.open...iv/tvurceVysledku	Padělková, Zdeňka Růžička, Aleš Chlupatý, Tomáš Nevoralová, Jana
http://linked.open...ain/vavai/riv/wos	000326112700027
issn	0022-328X
number of pages	4 (xsd:int)
http://bibframe.org/vocab/doi	10.1016/j.jorganchem.2013.07.067
http://localhost/t...ganizacniJednotka	25310

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