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| rdfs:seeAlso
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| Description
| - Reactions of bis[bis(trimethylsilyl)amino]tin and the dimer of [bis(trimethylsilyl)amino]tin chloride with various carbodiimides give pure corresponding tin(II) guanidinates in essentially quantitative yields. Heteroleptic bis(trimethylsilyl)amido ({R-NC[N-(SiMe3)(2)]N-R}SnN(SiMe3)(2))- and chloro-substituted ({R-NC}[N-(SiMe3)(2)]N-R}SnCl) tin(II) guanidinates were obtained from reactions of N,N'-diisopropyl-, N,N'-dicyclohexyl-, N,N'-bis(4-methylphenyl)-, and N-[3-(dimethylamino)propyl]-N'-ethylcarbodiimides, respectively. Homoleptic tin(II) guanidinates {R-NC[N(SiMe3)(2)]N-R}(2)Sn were obtained from the N,N'-bis(4-methylphenyl)- and N-[3-(dimethylamino)propyl]-N'-ethyl-substituted carbodiimides. Similar reactions of N,N'-bis(2,6-diisopropylphenyl)- and N,N'-bis(trimethylsilyl)carbodiimide, respectively, having the bulkiest substituents of the series, failed to take place under various conditions. The complexes prepared were characterized as monomers in solution by H-1, C-13, and Sn-119 NMR spectroscopy in C6D6 and THF-d(8). The solid-state NMR spectra were recorded for structure comparison. X-ray diffraction studies of one homoleptic monomer, two heteroleptic chloro complexes with the structures of two different types of dimers, and the oxidation product of the heteroleptic bis(trimethylsilyl)amido-substituted guanidinate-a centrosymmetric (guanidinato)tin(IV) oxide-were performed on appropriate crystals. Attempts to prepare homoleptic types of isopropyl- and cyclohexyl-substituted tin(II) guanidinate complexes were unsuccessful. The structures were also evaluated by DFT methods.
- Reactions of bis[bis(trimethylsilyl)amino]tin and the dimer of [bis(trimethylsilyl)amino]tin chloride with various carbodiimides give pure corresponding tin(II) guanidinates in essentially quantitative yields. Heteroleptic bis(trimethylsilyl)amido ({R-NC[N-(SiMe3)(2)]N-R}SnN(SiMe3)(2))- and chloro-substituted ({R-NC}[N-(SiMe3)(2)]N-R}SnCl) tin(II) guanidinates were obtained from reactions of N,N'-diisopropyl-, N,N'-dicyclohexyl-, N,N'-bis(4-methylphenyl)-, and N-[3-(dimethylamino)propyl]-N'-ethylcarbodiimides, respectively. Homoleptic tin(II) guanidinates {R-NC[N(SiMe3)(2)]N-R}(2)Sn were obtained from the N,N'-bis(4-methylphenyl)- and N-[3-(dimethylamino)propyl]-N'-ethyl-substituted carbodiimides. Similar reactions of N,N'-bis(2,6-diisopropylphenyl)- and N,N'-bis(trimethylsilyl)carbodiimide, respectively, having the bulkiest substituents of the series, failed to take place under various conditions. The complexes prepared were characterized as monomers in solution by H-1, C-13, and Sn-119 NMR spectroscopy in C6D6 and THF-d(8). The solid-state NMR spectra were recorded for structure comparison. X-ray diffraction studies of one homoleptic monomer, two heteroleptic chloro complexes with the structures of two different types of dimers, and the oxidation product of the heteroleptic bis(trimethylsilyl)amido-substituted guanidinate-a centrosymmetric (guanidinato)tin(IV) oxide-were performed on appropriate crystals. Attempts to prepare homoleptic types of isopropyl- and cyclohexyl-substituted tin(II) guanidinate complexes were unsuccessful. The structures were also evaluated by DFT methods. (en)
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| Title
| - Addition of Lappert's stannylenes to carbodiimides, providing a new class of tin(II) guanidinates
- Addition of Lappert's stannylenes to carbodiimides, providing a new class of tin(II) guanidinates (en)
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| skos:prefLabel
| - Addition of Lappert's stannylenes to carbodiimides, providing a new class of tin(II) guanidinates
- Addition of Lappert's stannylenes to carbodiimides, providing a new class of tin(II) guanidinates (en)
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| skos:notation
| - RIV/00216275:25310/12:39895768!RIV13-GA0-25310___
|
| http://linked.open...avai/riv/aktivita
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| http://linked.open...avai/riv/aktivity
| - I, P(GA104/09/0829), P(GPP207/10/P092), S
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| http://linked.open...iv/cisloPeriodika
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| http://linked.open...vai/riv/dodaniDat
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| http://linked.open...aciTvurceVysledku
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| http://linked.open.../riv/druhVysledku
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| http://linked.open...iv/duvernostUdaju
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| http://linked.open...titaPredkladatele
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| http://linked.open...dnocenehoVysledku
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| http://linked.open...ai/riv/idVysledku
| - RIV/00216275:25310/12:39895768
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| http://linked.open...riv/jazykVysledku
| |
| http://linked.open.../riv/klicovaSlova
| - aryl halide; earth-metals; transition-metals; heterocyclic carbenes; metaethical exchange; structural-characterization; crystal-structure; heterocumulene metathesis; Gaussian-basis sets; correlated molecular calculations (en)
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| http://linked.open.../riv/klicoveSlovo
| |
| http://linked.open...odStatuVydavatele
| - US - Spojené státy americké
|
| http://linked.open...ontrolniKodProRIV
| |
| http://linked.open...i/riv/nazevZdroje
| |
| http://linked.open...in/vavai/riv/obor
| |
| http://linked.open...ichTvurcuVysledku
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| http://linked.open...cetTvurcuVysledku
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| http://linked.open...vavai/riv/projekt
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| http://linked.open...UplatneniVysledku
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| http://linked.open...v/svazekPeriodika
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| http://linked.open...iv/tvurceVysledku
| - Padělková, Zdeňka
- Růžička, Aleš
- Chlupatý, Tomáš
- DeProft, Frank
- Willem, Rudolph
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| http://linked.open...ain/vavai/riv/wos
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| issn
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| number of pages
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| http://bibframe.org/vocab/doi
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| http://localhost/t...ganizacniJednotka
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