About: Reactivity of NCN-Chelated (NCN = C6H3-2,6-(CH2NMe2)(2)) Antimony(III) and Bismuth(III) Oxides toward Oxides of Arsenic

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About: Reactivity of NCN-Chelated (NCN = C6H3-2,6-(CH2NMe2)(2)) Antimony(III) and Bismuth(III) Oxides toward Oxides of Arsenic Goto Sponge NotDistinct Permalink

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	Organoantimony(III) and organobismuth(III) oxides (LMO)(2) (where L is the NCN-chelating ligand C6H3-2,6-(CH2NMe2)(2) and M = Sb (1), Bi (2)) reacted smoothly with arsenic oxides As2O5 and As2O3 to form the molecular oxides [(LM)(3)(AsO4)(2)] and [(LM)(2)(As2O5)] (where M = Sb (3, 5), Bi (4, 6)). All compounds were characterized by electrospray ionization (ESI) mass spectrometry, nuclear magnetic resonance (NMR) spectroscopy, and, in the case of and 6, single-crystal X-ray diffraction (XRD) analyses. Compound 3 formed two conformational isomers in a benzene or chloroform solution, as confirmed by H-1 and C-13 NMR spectroscopy. As in the case of 3, 5 also formed conformational isomers in a benzene solution, whereas the bismuth analogue 6 was unstable in solution. The stabilities of the three possible conformers of 5 were studied by density functional theory (DFT) calculations. Organoantimony(III) and organobismuth(III) oxides (LMO)(2) (where L is the NCN-chelating ligand C6H3-2,6-(CH2NMe2)(2) and M = Sb (1), Bi (2)) reacted smoothly with arsenic oxides As2O5 and As2O3 to form the molecular oxides [(LM)(3)(AsO4)(2)] and [(LM)(2)(As2O5)] (where M = Sb (3, 5), Bi (4, 6)). All compounds were characterized by electrospray ionization (ESI) mass spectrometry, nuclear magnetic resonance (NMR) spectroscopy, and, in the case of and 6, single-crystal X-ray diffraction (XRD) analyses. Compound 3 formed two conformational isomers in a benzene or chloroform solution, as confirmed by H-1 and C-13 NMR spectroscopy. As in the case of 3, 5 also formed conformational isomers in a benzene solution, whereas the bismuth analogue 6 was unstable in solution. The stabilities of the three possible conformers of 5 were studied by density functional theory (DFT) calculations. (en)
Title	Reactivity of NCN-Chelated (NCN = C6H3-2,6-(CH2NMe2)(2)) Antimony(III) and Bismuth(III) Oxides toward Oxides of Arsenic Reactivity of NCN-Chelated (NCN = C6H3-2,6-(CH2NMe2)(2)) Antimony(III) and Bismuth(III) Oxides toward Oxides of Arsenic (en)
skos:prefLabel	Reactivity of NCN-Chelated (NCN = C6H3-2,6-(CH2NMe2)(2)) Antimony(III) and Bismuth(III) Oxides toward Oxides of Arsenic Reactivity of NCN-Chelated (NCN = C6H3-2,6-(CH2NMe2)(2)) Antimony(III) and Bismuth(III) Oxides toward Oxides of Arsenic (en)
skos:notation	RIV/00216275:25310/12:39895564!RIV13-GA0-25310___
http://linked.open...avai/riv/aktivita	I P S
http://linked.open...avai/riv/aktivity	I, P(GAP106/10/0443), S
http://linked.open...iv/cisloPeriodika	5
http://linked.open...vai/riv/dodaniDat	2013
http://linked.open...aciTvurceVysledku	Dostál, Libor Růžička, Aleš Jambor, Roman Svoboda, Tomáš Jirásko, Robert Lyčka, Antonín
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Univerzita Pardubice / Fakulta chemicko-technologická
http://linked.open...dnocenehoVysledku	164202
http://linked.open...ai/riv/idVysledku	RIV/00216275:25310/12:39895564
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	PH; ORGANOANTIMONY(III); ELEMENTS; CRYSTAL-STRUCTURES; GAUSSIAN-BASIS SETS; CORRELATED MOLECULAR CALCULATIONS; BOND COVALENT RADII (en)
http://linked.open.../riv/klicoveSlovo	BOND COVALENT RADII CORRELATED MOLECULAR CALCULATIONS GAUSSIAN-BASIS SETS ORGANOANTIMONY(III) PH CRYSTAL-STRUCTURES ELEMENTS
http://linked.open...odStatuVydavatele	US - Spojené státy americké
http://linked.open...ontrolniKodProRIV	[CE1C53A293EC]
http://linked.open...i/riv/nazevZdroje	Organometallics
http://linked.open...in/vavai/riv/obor	CA
http://linked.open...ichTvurcuVysledku	6 (xsd:int)
http://linked.open...cetTvurcuVysledku	7 (xsd:int)
http://linked.open...vavai/riv/projekt	Organometallic chalcogenides of 14 and 15 group as nanodimensional and MOCVD materials
http://linked.open...UplatneniVysledku	2012
http://linked.open...v/svazekPeriodika	31
http://linked.open...iv/tvurceVysledku	Dostál, Libor Jambor, Roman Růžička, Aleš Svoboda, Tomáš Jirásko, Robert Lyčka, Antonín De Proft, Frank
http://linked.open...ain/vavai/riv/wos	000301331200019
issn	0276-7333
number of pages	5 (xsd:int)
http://bibframe.org/vocab/doi	10.1021/om201025d
http://localhost/t...ganizacniJednotka	25310

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