About: Bismuth-Modified and the Native Tricresyl Phosphate-Based Carbon Paste Electrode for the Determination of Two Different Pesticides

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	In this article, the voltammetric responses of the bismuth powder bulk-modified tricresyl phosphate-based carbon paste electrode (Bi5%-C/TCP, where 5% is the content of pulverized metal), surface-modified, bismuth film-plated BiF-C/TCP), and the unmodified carbon paste electrode of the C/TCP type were studied and subsequently optimized for the cathodic determination of Imidacloprid (IMI), an insecticide reducible in a fairly negative potential range. The individual comparisons have shown that the determination of IMI is more efficient with the Bi5%-C/TCP or Bi20%-C/TCP, respectively, by the direct cathodic differential pulse voltammetry (DPV). Concerning the determination of Carbendazim (CBZ), a fungicide oxidizable at the positive potentials, the unmodified C/TCP was applied to the determination in the differential pulse anodic stripping voltammetric mode. The respective LODs were at the low mýg mL-1 level for IMI or even down to the ng mL-1 for a more sensitive determination of CBZ. In this article, the voltammetric responses of the bismuth powder bulk-modified tricresyl phosphate-based carbon paste electrode (Bi5%-C/TCP, where 5% is the content of pulverized metal), surface-modified, bismuth film-plated BiF-C/TCP), and the unmodified carbon paste electrode of the C/TCP type were studied and subsequently optimized for the cathodic determination of Imidacloprid (IMI), an insecticide reducible in a fairly negative potential range. The individual comparisons have shown that the determination of IMI is more efficient with the Bi5%-C/TCP or Bi20%-C/TCP, respectively, by the direct cathodic differential pulse voltammetry (DPV). Concerning the determination of Carbendazim (CBZ), a fungicide oxidizable at the positive potentials, the unmodified C/TCP was applied to the determination in the differential pulse anodic stripping voltammetric mode. The respective LODs were at the low mýg mL-1 level for IMI or even down to the ng mL-1 for a more sensitive determination of CBZ. (en)
Title	Bismuth-Modified and the Native Tricresyl Phosphate-Based Carbon Paste Electrode for the Determination of Two Different Pesticides Bismuth-Modified and the Native Tricresyl Phosphate-Based Carbon Paste Electrode for the Determination of Two Different Pesticides (en)
skos:prefLabel	Bismuth-Modified and the Native Tricresyl Phosphate-Based Carbon Paste Electrode for the Determination of Two Different Pesticides Bismuth-Modified and the Native Tricresyl Phosphate-Based Carbon Paste Electrode for the Determination of Two Different Pesticides (en)
skos:notation	RIV/00216275:25310/12:39895507!RIV13-MSM-25310___
http://linked.open...avai/riv/aktivita	I P
http://linked.open...avai/riv/aktivity	I, P(LC06035)
http://linked.open...vai/riv/dodaniDat	2013
http://linked.open...aciTvurceVysledku	Švancara, Ivan Vytřas, Karel Ashrafi, Amirmansoor
http://linked.open.../riv/druhVysledku	D - Článek ve sborníku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Univerzita Pardubice / Fakulta chemicko-technologická
http://linked.open...dnocenehoVysledku	125227
http://linked.open...ai/riv/idVysledku	RIV/00216275:25310/12:39895507
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	Carbendazim (CBZ); Imidacloprid (IMI); voltammetric determination; unmodifed form; two bismuth-modified variants; Tricresyl phosphate-based carbon paste (en)
http://linked.open.../riv/klicoveSlovo	Carbendazim (CBZ) Imidacloprid (IMI) Tricresyl phosphate-based carbon paste two bismuth-modified variants unmodifed form voltammetric determination
http://linked.open...ontrolniKodProRIV	[284CE816927E]
http://linked.open...v/mistoKonaniAkce	Pardubice
http://linked.open...i/riv/mistoVydani	Pardubice
http://linked.open...i/riv/nazevZdroje	Sensing in Electroanalysis Vol. 7
http://linked.open...in/vavai/riv/obor	CG
http://linked.open...ichTvurcuVysledku	3 (xsd:int)
http://linked.open...cetTvurcuVysledku	8 (xsd:int)
http://linked.open...vavai/riv/projekt	Centre of Biophysical Chemistry, Bioelectrochemistry and Bioanalysis. New Tools for Genomics, Proteomics and Biomedicine.
http://linked.open...UplatneniVysledku	2012
http://linked.open...iv/tvurceVysledku	Guzsvány, Valéria Papp, Zsigmond Vytřas, Karel Švancara, Ivan Ashrafi, Amirmansoor Rodić, Marko Trtić-Petrović, Tatjana Đorđević, Jelena
http://linked.open...vavai/riv/typAkce	EUR - Evropská
http://linked.open.../riv/zahajeniAkce	2012-11-14 (xsd:date)
number of pages	17 (xsd:int)
http://purl.org/ne...btex#hasPublisher	Univerzita Pardubice
https://schema.org/isbn	978-80-7395-563-2
http://localhost/t...ganizacniJednotka	25310

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