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  • The aim of the work was to evaluate the efficiency and selectivity of selected columns for reversed-phase liquid chromatography packed with the porous shell particles. Kinetic properties of porous shell particles, dependent on band broadening of the solute, were evaluated using series of homologic alkylbenzenes. It is possible to express thermodynamic properties of separation by selectivity. Specific interactions contributing to the selectivity of separation of 23 phenol derivatives were evaluated using linear free energy relationship model (LFER) employing molecular structural descriptors. Similarities and differences between the columns were classified using multiple linear regressions of retention data and cluster analysis based on the similarity dendrograms. Two columns with the most different retention mechanism can be employed for orthogonal separations in two-dimensional system. The differences in selectivity are illustrated in separation with gradient elution of mixture of phenol derivatives.
  • The aim of the work was to evaluate the efficiency and selectivity of selected columns for reversed-phase liquid chromatography packed with the porous shell particles. Kinetic properties of porous shell particles, dependent on band broadening of the solute, were evaluated using series of homologic alkylbenzenes. It is possible to express thermodynamic properties of separation by selectivity. Specific interactions contributing to the selectivity of separation of 23 phenol derivatives were evaluated using linear free energy relationship model (LFER) employing molecular structural descriptors. Similarities and differences between the columns were classified using multiple linear regressions of retention data and cluster analysis based on the similarity dendrograms. Two columns with the most different retention mechanism can be employed for orthogonal separations in two-dimensional system. The differences in selectivity are illustrated in separation with gradient elution of mixture of phenol derivatives. (en)
Title
  • Kinetic and Thermodynamic Properties of Porous Shell Particles LC Stationary Phases
  • Kinetic and Thermodynamic Properties of Porous Shell Particles LC Stationary Phases (en)
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  • Kinetic and Thermodynamic Properties of Porous Shell Particles LC Stationary Phases
  • Kinetic and Thermodynamic Properties of Porous Shell Particles LC Stationary Phases (en)
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  • RIV/00216275:25310/12:39895477!RIV13-MSM-25310___
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  • 144648
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  • RIV/00216275:25310/12:39895477
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  • linear free energy relationship model; selectivity; phenol derivatives; efficiency; porous shell particles (en)
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  • [B2CF2A86A99B]
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  • Brno
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  • Brno
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  • CECE 2012: 9th International Interdisciplinary Meeting on Bioanalysis
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  • Fischer, Jan
  • Česla, Petr
  • Vaňková, Nikola
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  • Ústav analytické chemie AV ČR, v. v. i.
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  • 978-80-904959-1-3
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  • 25310
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