About: Effect of the substitution on the protonation of allyl cyclopentadienyl molybdenum(II) compounds

Facets (new session)
Description
Metadata
Settings
- owl:sameAs
- Inference Rule:

About: Effect of the substitution on the protonation of allyl cyclopentadienyl molybdenum(II) compounds Goto Sponge NotDistinct Permalink

An Entity of Type : http://linked.opendata.cz/ontology/domain/vavai/Vysledek, within Data Space : linked.opendata.cz associated with source document(s)

Attributes	Values
rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
rdfs:seeAlso	http://pubs.acs.org/doi/abs/10.1021/om2010244
Description	Synthesis, characterization, and reactivity of new allyl cyclopentadienyl molybdenum(II) compounds [eta(3)-C3H4R1)(eta(5)-C5H3(R-2)(2))Mo(CO)(2)] (R-1 = H, COOMe; R-2 = COOMe, (CONHBu)-Bu-t) are reported. Although these compounds are structural analogues of [eta(3)-C3H5)(eta(5)-Cp)Mo-(CO)(2)], their reactivity is very different. While protonation of [(eta(3)-C3H5)(eta(5)-CP)Mo(CO)(2)] gives a cationic cyclopentadienyl complex, the presented compounds give cationic ally! complexes [(eta(3)-C3H4R)Mo(CO)(2)(NCMe)(3)][BF4] (R = H, COOMe) or stable cationic ally! cyclopentadienyl complexes. The theoretical calculations have shown that this behavior is a result of high affinity of the functional groups in the cyclopentadienyl ligand toward protonation. Synthesis, characterization, and reactivity of new allyl cyclopentadienyl molybdenum(II) compounds [eta(3)-C3H4R1)(eta(5)-C5H3(R-2)(2))Mo(CO)(2)] (R-1 = H, COOMe; R-2 = COOMe, (CONHBu)-Bu-t) are reported. Although these compounds are structural analogues of [eta(3)-C3H5)(eta(5)-Cp)Mo-(CO)(2)], their reactivity is very different. While protonation of [(eta(3)-C3H5)(eta(5)-CP)Mo(CO)(2)] gives a cationic cyclopentadienyl complex, the presented compounds give cationic ally! complexes [(eta(3)-C3H4R)Mo(CO)(2)(NCMe)(3)][BF4] (R = H, COOMe) or stable cationic ally! cyclopentadienyl complexes. The theoretical calculations have shown that this behavior is a result of high affinity of the functional groups in the cyclopentadienyl ligand toward protonation. (en)
Title	Effect of the substitution on the protonation of allyl cyclopentadienyl molybdenum(II) compounds Effect of the substitution on the protonation of allyl cyclopentadienyl molybdenum(II) compounds (en)
skos:prefLabel	Effect of the substitution on the protonation of allyl cyclopentadienyl molybdenum(II) compounds Effect of the substitution on the protonation of allyl cyclopentadienyl molybdenum(II) compounds (en)
skos:notation	RIV/00216275:25310/12:39895346!RIV13-MSM-25310___
http://linked.open...avai/riv/aktivita	I
http://linked.open...avai/riv/aktivity	I
http://linked.open...iv/cisloPeriodika	6
http://linked.open...vai/riv/dodaniDat	2013
http://linked.open...aciTvurceVysledku	Vinklárek, Jaromír Eisner, Aleš Padělková, Zdeňka Honzíček, Jan
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Univerzita Pardubice / Fakulta chemicko-technologická
http://linked.open...dnocenehoVysledku	133331
http://linked.open...ai/riv/idVysledku	RIV/00216275:25310/12:39895346
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	polarization functions; molybdocene dichloride; coordination chemistry; organometallic chemistry; mixed-ring; aqueous-solutions; Tungsten complexes; Gaussian-type basis; molecular-orbital methods; effective core potentials (en)
http://linked.open.../riv/klicoveSlovo	molecular-orbital methods Gaussian-type basis Tungsten complexes aqueous-solutions coordination chemistry effective core potentials mixed-ring molybdocene dichloride organometallic chemistry polarization functions
http://linked.open...odStatuVydavatele	US - Spojené státy americké
http://linked.open...ontrolniKodProRIV	[DA0FB246318F]
http://linked.open...i/riv/nazevZdroje	Organometallics
http://linked.open...in/vavai/riv/obor	CA
http://linked.open...ichTvurcuVysledku	4 (xsd:int)
http://linked.open...cetTvurcuVysledku	5 (xsd:int)
http://linked.open...UplatneniVysledku	2012
http://linked.open...v/svazekPeriodika	31
http://linked.open...iv/tvurceVysledku	Padělková, Zdeňka Vinklárek, Jaromír Eisner, Aleš Kratochvíl, Pavel Honzíček, Jan
http://linked.open...ain/vavai/riv/wos	000301895900009
issn	0276-7333
number of pages	10 (xsd:int)
http://bibframe.org/vocab/doi	10.1021/om2010244
http://localhost/t...ganizacniJednotka	25310

Faceted Search & Find service v1.16.118 as of Jun 21 2024

Alternative Linked Data Documents: ODE Content Formats:

RDF

ODATA

Microdata

About

OpenLink Virtuoso version 07.20.3240 as of Jun 21 2024, on Linux (x86_64-pc-linux-gnu), Single-Server Edition (126 GB total memory, 58 GB memory in use)
Data on this page belongs to its respective rights holders.
Virtuoso Faceted Browser Copyright © 2009-2024 OpenLink Software