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  • In this paper, several fundamental investigations published over the past decades with regard to the thermal analysis of polymer-based explosives (PBXs) have been briefly reviewed. A number of explosive fillers and polymer bases that were used as their main ingredients of PBXs are summarized herein. In addition, the calculation methods for their decomposition kinetics and thermal stability parameters are also introduced in detail. It was concluded that only PBXs based on HMX, RDX and TATB have been widely investigated, and that some other PBXs containing innovative fillers, such as CL-20, TNAZ, NTO and BCHMX are at the design stage. The isoconversional methods and model fitting procedures are usually used to analyze the discrete thermolysis processes of PBXs. In addition, their thermal stability parameters such as shelf life, explosion delay, critical temperature. thermostability threshold, 500-day cookoff temperature and approximate time to explosion could be calculated easily from the kinetic data.
  • In this paper, several fundamental investigations published over the past decades with regard to the thermal analysis of polymer-based explosives (PBXs) have been briefly reviewed. A number of explosive fillers and polymer bases that were used as their main ingredients of PBXs are summarized herein. In addition, the calculation methods for their decomposition kinetics and thermal stability parameters are also introduced in detail. It was concluded that only PBXs based on HMX, RDX and TATB have been widely investigated, and that some other PBXs containing innovative fillers, such as CL-20, TNAZ, NTO and BCHMX are at the design stage. The isoconversional methods and model fitting procedures are usually used to analyze the discrete thermolysis processes of PBXs. In addition, their thermal stability parameters such as shelf life, explosion delay, critical temperature. thermostability threshold, 500-day cookoff temperature and approximate time to explosion could be calculated easily from the kinetic data. (en)
Title
  • Recent advances in thermal analysis and stability evaluation of insensitive plastic bonded explosives (PBXs)
  • Recent advances in thermal analysis and stability evaluation of insensitive plastic bonded explosives (PBXs) (en)
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  • Recent advances in thermal analysis and stability evaluation of insensitive plastic bonded explosives (PBXs)
  • Recent advances in thermal analysis and stability evaluation of insensitive plastic bonded explosives (PBXs) (en)
skos:notation
  • RIV/00216275:25310/12:39895287!RIV13-MV0-25310___
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(VG20102014032), S
http://linked.open...iv/cisloPeriodika
  • 6
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
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  • 164312
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  • RIV/00216275:25310/12:39895287
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  • thermal stability; thermal analysis; PBX; explosive; energetic materials (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • NL - Nizozemsko
http://linked.open...ontrolniKodProRIV
  • [04BC126B66AA]
http://linked.open...i/riv/nazevZdroje
  • Thermochimica Acta
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http://linked.open...ichTvurcuVysledku
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http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 537
http://linked.open...iv/tvurceVysledku
  • Elbeih, Ahmed Ikhlas Mohamed
  • Zeman, Svatopluk
  • Qilong, Yan
http://linked.open...ain/vavai/riv/wos
  • 000304026100001
issn
  • 0040-6031
number of pages
http://bibframe.org/vocab/doi
  • 10.1016/j.tca.2012.03.009
http://localhost/t...ganizacniJednotka
  • 25310
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