About: The Effect of Acetate Concentration, Solution pH and Conductivity on the Anodic Stripping Voltammetry of Lead and Cadmium Ions at in situ Bismuth-Plated Carbon Microelectrodes.

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About: The Effect of Acetate Concentration, Solution pH and Conductivity on the Anodic Stripping Voltammetry of Lead and Cadmium Ions at in situ Bismuth-Plated Carbon Microelectrodes. Goto Sponge NotDistinct Permalink

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	The use of carbon microdisc electrode substrates allowed Pb(II) and Cd(II) anodic stripping voltammetry at in situ plated bismuth films to be studied in an extended acetate buffer/electrolyte concentration range that includes very low or zero acetate levels. The change of the Pb and Cd square wave anodic stripping voltammetry (SWASV) peak height with acetate concentration, pH and conductivity has been studied systematically. It was found that the stripping peak signal is considerably enhanced in the absence of added acetate or in acidic solutions. This behaviour has been attributed to the extent of metal ion complexation values. Recording both the forward and the reverse voltammograms of each SWASV curve, the signal variation could be attributed to changes in the metal ion deposition rate (as its complexation state is varied) both during the preconcentration step and the reverse pulse of the SWASV potential sequence. The use of carbon microdisc electrode substrates allowed Pb(II) and Cd(II) anodic stripping voltammetry at in situ plated bismuth films to be studied in an extended acetate buffer/electrolyte concentration range that includes very low or zero acetate levels. The change of the Pb and Cd square wave anodic stripping voltammetry (SWASV) peak height with acetate concentration, pH and conductivity has been studied systematically. It was found that the stripping peak signal is considerably enhanced in the absence of added acetate or in acidic solutions. This behaviour has been attributed to the extent of metal ion complexation values. Recording both the forward and the reverse voltammograms of each SWASV curve, the signal variation could be attributed to changes in the metal ion deposition rate (as its complexation state is varied) both during the preconcentration step and the reverse pulse of the SWASV potential sequence. (en)
Title	The Effect of Acetate Concentration, Solution pH and Conductivity on the Anodic Stripping Voltammetry of Lead and Cadmium Ions at in situ Bismuth-Plated Carbon Microelectrodes. The Effect of Acetate Concentration, Solution pH and Conductivity on the Anodic Stripping Voltammetry of Lead and Cadmium Ions at in situ Bismuth-Plated Carbon Microelectrodes. (en)
skos:prefLabel	The Effect of Acetate Concentration, Solution pH and Conductivity on the Anodic Stripping Voltammetry of Lead and Cadmium Ions at in situ Bismuth-Plated Carbon Microelectrodes. The Effect of Acetate Concentration, Solution pH and Conductivity on the Anodic Stripping Voltammetry of Lead and Cadmium Ions at in situ Bismuth-Plated Carbon Microelectrodes. (en)
skos:notation	RIV/00216275:25310/11:39892620!RIV12-MSM-25310___
http://linked.open...avai/riv/aktivita	Z
http://linked.open...avai/riv/aktivity	Z(MSM 253100002)
http://linked.open...iv/cisloPeriodika	1
http://linked.open...vai/riv/dodaniDat	2012
http://linked.open...aciTvurceVysledku	Baldrianová, Lucie Švancara, Ivan
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Univerzita Pardubice / Fakulta chemicko-technologická
http://linked.open...dnocenehoVysledku	196162
http://linked.open...ai/riv/idVysledku	RIV/00216275:25310/11:39892620
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	Acetate; Anodic stripping voltammetry; Microelectrodes; Bismuth film electrodes (en)
http://linked.open.../riv/klicoveSlovo	Anodic stripping voltammetry Acetate Bismuth film electrodes Microelectrodes
http://linked.open...odStatuVydavatele	CH - Švýcarská konfederace
http://linked.open...ontrolniKodProRIV	[6BA2ADD867BA]
http://linked.open...i/riv/nazevZdroje	Journal of Electroanalytical Chemistry
http://linked.open...in/vavai/riv/obor	CG
http://linked.open...ichTvurcuVysledku	2 (xsd:int)
http://linked.open...cetTvurcuVysledku	5 (xsd:int)
http://linked.open...UplatneniVysledku	2011
http://linked.open...v/svazekPeriodika	660
http://linked.open...iv/tvurceVysledku	Baldrianová, Lucie Švancara, Ivan Agrafiotou, P. Jannakoudakis, A. D. Sotiropoulos, S.
http://linked.open...ain/vavai/riv/wos	000295149600006
http://linked.open...n/vavai/riv/zamer	http://linked.opendata.cz/resource/domain/vavai/zamer/MSM%20253100002
issn	1572-6657
number of pages	6 (xsd:int)
http://bibframe.org/vocab/doi	10.1016/j.jelechem.2011.05.028
http://localhost/t...ganizacniJednotka	25310

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