About: Voltammetric Monitoring of Photodegradation of Clothianidin, Nitenpyram and Imidacloprid Insecticides Using a Tricresyl Phosphate-Based Carbon Paste Electrode     Goto   Sponge   NotDistinct   Permalink

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Description
  • A voltammetric investigation of two commercial neonicitinoid insecticides, Clothianidin (Clo) and Nitenpyram (Nit), was carried out and completed with the third one, Imidacloprid (Imc), from a previous study when using two different types of carbon paste electrodes made from graphite powder and silicone oil (SO-CPE) or tricresyl phosphate as the binder (TCP-CPE). For all substancec of interest, the latter has been found superior with respect to the signal-to-noise characteristics and the overall electroanalytical performance. Subsequently, a new method employing the direct differential pulse voltammetry (DPV) and the TCP-CPE has been proposed for the determination of Clo and Nit at the low ug mL-1 concentration level. Finally, the procedure could be applied for the monitoring of the photolytic and TiO2-assisted photocatalytic degradation of Clo, Nit, and Imc, when the quantitative and kinetic data obtained have agreed well with the results of the reference HPLC/DAD measurements.
  • A voltammetric investigation of two commercial neonicitinoid insecticides, Clothianidin (Clo) and Nitenpyram (Nit), was carried out and completed with the third one, Imidacloprid (Imc), from a previous study when using two different types of carbon paste electrodes made from graphite powder and silicone oil (SO-CPE) or tricresyl phosphate as the binder (TCP-CPE). For all substancec of interest, the latter has been found superior with respect to the signal-to-noise characteristics and the overall electroanalytical performance. Subsequently, a new method employing the direct differential pulse voltammetry (DPV) and the TCP-CPE has been proposed for the determination of Clo and Nit at the low ug mL-1 concentration level. Finally, the procedure could be applied for the monitoring of the photolytic and TiO2-assisted photocatalytic degradation of Clo, Nit, and Imc, when the quantitative and kinetic data obtained have agreed well with the results of the reference HPLC/DAD measurements. (en)
Title
  • Voltammetric Monitoring of Photodegradation of Clothianidin, Nitenpyram and Imidacloprid Insecticides Using a Tricresyl Phosphate-Based Carbon Paste Electrode
  • Voltammetric Monitoring of Photodegradation of Clothianidin, Nitenpyram and Imidacloprid Insecticides Using a Tricresyl Phosphate-Based Carbon Paste Electrode (en)
skos:prefLabel
  • Voltammetric Monitoring of Photodegradation of Clothianidin, Nitenpyram and Imidacloprid Insecticides Using a Tricresyl Phosphate-Based Carbon Paste Electrode
  • Voltammetric Monitoring of Photodegradation of Clothianidin, Nitenpyram and Imidacloprid Insecticides Using a Tricresyl Phosphate-Based Carbon Paste Electrode (en)
skos:notation
  • RIV/00216275:25310/11:39892619!RIV12-MSM-25310___
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(LC06035), Z(MSM0021627502)
http://linked.open...iv/cisloPeriodika
  • 11
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 239521
http://linked.open...ai/riv/idVysledku
  • RIV/00216275:25310/11:39892619
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • TiO2-assisted photocatalysis; Photolysis; Tricresyl phosphate-based carbon paste electrode; Differential pulse voltammetry; Neonicotinoids (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • CS - Státní svaz Srbska a Černé Hory
http://linked.open...ontrolniKodProRIV
  • [E21D3E643E49]
http://linked.open...i/riv/nazevZdroje
  • International Journal of Electrochemical Science
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 6
http://linked.open...iv/tvurceVysledku
  • Guzsvány, Valéria
  • Papp, Zsigmond
  • Vytřas, Karel
  • Švancara, Ivan
http://linked.open...ain/vavai/riv/wos
  • 000297503300005
http://linked.open...n/vavai/riv/zamer
issn
  • 1452-3981
number of pages
http://localhost/t...ganizacniJednotka
  • 25310
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