About: Dichloridobis{2-[(dimethylamino)methyl]phenyl}bis{2-[(dimethylazaniumyl)methyl]phenyl} di-mý-hydroxido-di-mý(3)-oxido-tertaphenyltetratin(IV) dichloride deuterochloroform decasolvate.     Goto   Sponge   NotDistinct   Permalink

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Description
  • The ladder-like structure of the tetranuclear title compound, [Sn(4)(C(6)H(5))(4)Cl(2)O(2)(OH)(2)(C(9)H(13)N)(2)(C(9)H(12)N)(2)]Cl(2)?10CDCl(3), consists of two five- and two six-coordinated Sn(IV) atoms bridged by oxide or hydroxide groups. The chelating ligands reveal rather strong Sn-N bonds [2.517(4)?], but the protonated dimethylamino groups in the periphery of the complex show no interaction with the metal atoms. The complex cation is located on an inversion centre. The chloride anion is linked to the complex molecule by strong intramolecular O-H???Cl and N-H???Cl hydrogen bonds. Five independent deuterochloroform accompany the complex, two of them are disordered [occupancy ratios 0.63 (2):0.27 (2) and 0.60 (2):0.40 (2)].
  • The ladder-like structure of the tetranuclear title compound, [Sn(4)(C(6)H(5))(4)Cl(2)O(2)(OH)(2)(C(9)H(13)N)(2)(C(9)H(12)N)(2)]Cl(2)?10CDCl(3), consists of two five- and two six-coordinated Sn(IV) atoms bridged by oxide or hydroxide groups. The chelating ligands reveal rather strong Sn-N bonds [2.517(4)?], but the protonated dimethylamino groups in the periphery of the complex show no interaction with the metal atoms. The complex cation is located on an inversion centre. The chloride anion is linked to the complex molecule by strong intramolecular O-H???Cl and N-H???Cl hydrogen bonds. Five independent deuterochloroform accompany the complex, two of them are disordered [occupancy ratios 0.63 (2):0.27 (2) and 0.60 (2):0.40 (2)]. (en)
Title
  • Dichloridobis{2-[(dimethylamino)methyl]phenyl}bis{2-[(dimethylazaniumyl)methyl]phenyl} di-mý-hydroxido-di-mý(3)-oxido-tertaphenyltetratin(IV) dichloride deuterochloroform decasolvate.
  • Dichloridobis{2-[(dimethylamino)methyl]phenyl}bis{2-[(dimethylazaniumyl)methyl]phenyl} di-mý-hydroxido-di-mý(3)-oxido-tertaphenyltetratin(IV) dichloride deuterochloroform decasolvate. (en)
skos:prefLabel
  • Dichloridobis{2-[(dimethylamino)methyl]phenyl}bis{2-[(dimethylazaniumyl)methyl]phenyl} di-mý-hydroxido-di-mý(3)-oxido-tertaphenyltetratin(IV) dichloride deuterochloroform decasolvate.
  • Dichloridobis{2-[(dimethylamino)methyl]phenyl}bis{2-[(dimethylazaniumyl)methyl]phenyl} di-mý-hydroxido-di-mý(3)-oxido-tertaphenyltetratin(IV) dichloride deuterochloroform decasolvate. (en)
skos:notation
  • RIV/00216275:25310/11:39892432!RIV12-GA0-25310___
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(GPP207/10/P092), Z(MSM0021627501)
http://linked.open...iv/cisloPeriodika
  • December
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 194330
http://linked.open...ai/riv/idVysledku
  • RIV/00216275:25310/11:39892432
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • X-ray; tin(IV) complex (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • DK - Dánské království
http://linked.open...ontrolniKodProRIV
  • [613F676013CD]
http://linked.open...i/riv/nazevZdroje
  • Acta Crystallographica Section E - Structure Reports Online
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 67
http://linked.open...iv/tvurceVysledku
  • Padělková, Zdeňka
  • Turek, Jan
http://linked.open...ain/vavai/riv/wos
  • 000298794900001
http://linked.open...n/vavai/riv/zamer
issn
  • 1600-5368
number of pages
http://bibframe.org/vocab/doi
  • 10.1107/S1600536811048872
http://localhost/t...ganizacniJednotka
  • 25310
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