About: Solvatochromism as an efficient tool to study N,N-dimethylamino- and cyano substituted pi-conjugated molecules with an intramolecular charge-transfer absorption

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About: Solvatochromism as an efficient tool to study N,N-dimethylamino- and cyano substituted pi-conjugated molecules with an intramolecular charge-transfer absorption Goto Sponge NotDistinct Permalink

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	A representative data set has been gained by the measurement of the electronic absorption spectra of twelve systematically selected push-pull systems with an intramolecular charge-transfer featuring electron-withdrawing CN groups, electron-donating N(CH3)2 groups, and various pi conjugated backbones in 32 solvents with different polarity. The most important characteristics of organic charge-transfer chromophores are the energy of the LUMO, the permanent dipole moment, the COSMO area, the COSMO volume, the number and ratio of N,N dimethylamino and cyano groups, and eventually the number of triple bonds. A representative data set has been gained by the measurement of the electronic absorption spectra of twelve systematically selected push-pull systems with an intramolecular charge-transfer featuring electron-withdrawing CN groups, electron-donating N(CH3)2 groups, and various pi conjugated backbones in 32 solvents with different polarity. The most important characteristics of organic charge-transfer chromophores are the energy of the LUMO, the permanent dipole moment, the COSMO area, the COSMO volume, the number and ratio of N,N dimethylamino and cyano groups, and eventually the number of triple bonds. (en)
Title	Solvatochromism as an efficient tool to study N,N-dimethylamino- and cyano substituted pi-conjugated molecules with an intramolecular charge-transfer absorption Solvatochromism as an efficient tool to study N,N-dimethylamino- and cyano substituted pi-conjugated molecules with an intramolecular charge-transfer absorption (en)
skos:prefLabel	Solvatochromism as an efficient tool to study N,N-dimethylamino- and cyano substituted pi-conjugated molecules with an intramolecular charge-transfer absorption Solvatochromism as an efficient tool to study N,N-dimethylamino- and cyano substituted pi-conjugated molecules with an intramolecular charge-transfer absorption (en)
skos:notation	RIV/00216275:25310/11:39892177!RIV12-MSM-25310___
http://linked.open...avai/riv/aktivita	Z
http://linked.open...avai/riv/aktivity	Z(MSM0021627501)
http://linked.open...iv/cisloPeriodika	4
http://linked.open...vai/riv/dodaniDat	2012
http://linked.open...aciTvurceVysledku	Bureš, Filip Pytela, Oldřich
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Univerzita Pardubice / Fakulta chemicko-technologická
http://linked.open...dnocenehoVysledku	230550
http://linked.open...ai/riv/idVysledku	RIV/00216275:25310/11:39892177
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	chromophore; donor-acceptor system; UV/Vis spectroscopy; solvatochromism; solvent effects (en)
http://linked.open.../riv/klicoveSlovo	UV/Vis spectroscopy donor-acceptor system solvatochromism solvent effects chromophore
http://linked.open...odStatuVydavatele	GB - Spojené království Velké Británie a Severního Irska
http://linked.open...ontrolniKodProRIV	[FD188690DA83]
http://linked.open...i/riv/nazevZdroje	Journal of Physical Organic Chemistry
http://linked.open...in/vavai/riv/obor	CC
http://linked.open...ichTvurcuVysledku	2 (xsd:int)
http://linked.open...cetTvurcuVysledku	4 (xsd:int)
http://linked.open...UplatneniVysledku	2011
http://linked.open...v/svazekPeriodika	24
http://linked.open...iv/tvurceVysledku	Bureš, Filip Pytela, Oldřich Diederich, François Kivala, Milan
http://linked.open...ain/vavai/riv/wos	000288965600003
http://linked.open...n/vavai/riv/zamer	Aimed preparation of special compounds and materials and investigation of their physical and chemical properties and supramolecular structures
issn	0894-3230
number of pages	7 (xsd:int)
http://bibframe.org/vocab/doi	10.1002/poc.1744
http://localhost/t...ganizacniJednotka	25310

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