About: Chromiumpentacarbonyl-Coordinated Organotin(II) Cation.     Goto   Sponge   NotDistinct   Permalink

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  • The synthesis of the novel chromiumpentacarbonyl complex [2,6-(MeOCH2)2- C6H3](Cl) SnCr(CO)5 (1) is reported. Compound 1 was used for the synthesis of novel chromiumpentacarbonyl coordinated organotin(II) cations [{2,6-(MeOCH2)2C6H3}SnCr-CO)5] (X = OTf or CB11H12). The strongly Lewis acidic tin(II) center of the latter organotin(II) cations coordinates H2O or THF molecules yielding the corresponding organotin(II) cations [{2,6-(MeOCH2)2C6H3}(H2O)SnCr(CO)5]? [OTf](2) and [{2,6-(MeOCH2)2C6H3}(H2O)SnCr(CO)5]? [CB11H12] (3). Compounds 13 were characterized by means of elemental analyses, 1H, 13C, 119Sn NMR spectroscopies, and single crystal X-ray diffraction analysis.
  • The synthesis of the novel chromiumpentacarbonyl complex [2,6-(MeOCH2)2- C6H3](Cl) SnCr(CO)5 (1) is reported. Compound 1 was used for the synthesis of novel chromiumpentacarbonyl coordinated organotin(II) cations [{2,6-(MeOCH2)2C6H3}SnCr-CO)5] (X = OTf or CB11H12). The strongly Lewis acidic tin(II) center of the latter organotin(II) cations coordinates H2O or THF molecules yielding the corresponding organotin(II) cations [{2,6-(MeOCH2)2C6H3}(H2O)SnCr(CO)5]? [OTf](2) and [{2,6-(MeOCH2)2C6H3}(H2O)SnCr(CO)5]? [CB11H12] (3). Compounds 13 were characterized by means of elemental analyses, 1H, 13C, 119Sn NMR spectroscopies, and single crystal X-ray diffraction analysis. (en)
Title
  • Chromiumpentacarbonyl-Coordinated Organotin(II) Cation.
  • Chromiumpentacarbonyl-Coordinated Organotin(II) Cation. (en)
skos:prefLabel
  • Chromiumpentacarbonyl-Coordinated Organotin(II) Cation.
  • Chromiumpentacarbonyl-Coordinated Organotin(II) Cation. (en)
skos:notation
  • RIV/00216275:25310/11:39892006!RIV12-GA0-25310___
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(GAP207/10/0215), Z(MSM0021627501)
http://linked.open...iv/cisloPeriodika
  • 8
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 190334
http://linked.open...ai/riv/idVysledku
  • RIV/00216275:25310/11:39892006
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • X ray; NMR; cation; organotin(II) (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • US - Spojené státy americké
http://linked.open...ontrolniKodProRIV
  • [B52B16D316F9]
http://linked.open...i/riv/nazevZdroje
  • Organometallics
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 30
http://linked.open...iv/tvurceVysledku
  • Dostál, Libor
  • Dostálová, Romana
  • Jambor, Roman
  • Růžička, Aleš
http://linked.open...ain/vavai/riv/wos
  • 000289501000039
http://linked.open...n/vavai/riv/zamer
issn
  • 0276-7333
number of pages
http://bibframe.org/vocab/doi
  • 10.1021/om200122m
http://localhost/t...ganizacniJednotka
  • 25310
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