About: Molybdenum complexes containing substituted cyclopenta[l]phenanthrenyl ligand

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	The synthesis of new cyclopenta[l]phenanthrenyl complexes [(C17H10Me)(C3H5)Mo(CO)2] and [(C17H9(COOMe)N(CH2)4)(C3H5)Mo(CO)2] is described. Although these compounds are structural analogues their reactivity is different. Protonation of [(C17H10Me)(C3H5)Mo(CO)2] gives a stable ionic compound [(C17H10Me)Mo(CO)2(NCMe)2][BF4] while its analogue containing both tertiary amino and carboxylic ester groups [(C17H9(COOMe)N(CH2)4)(C3H5)Mo(CO)2] decomposes under the same conditions. [(C17H10Me)Mo(CO)2(NCMe)2][BF4] reacts with cyclopentadiene to give a stable complex [(C5H6)(C17H10Me)Mo(CO)2][BF4] that was successfully oxidized to the Mo(IV) dicationic compound [(C5H5)(C17H10Me)Mo(CO)2][Br][BF4]. The synthesis of new cyclopenta[l]phenanthrenyl complexes [(C17H10Me)(C3H5)Mo(CO)2] and [(C17H9(COOMe)N(CH2)4)(C3H5)Mo(CO)2] is described. Although these compounds are structural analogues their reactivity is different. Protonation of [(C17H10Me)(C3H5)Mo(CO)2] gives a stable ionic compound [(C17H10Me)Mo(CO)2(NCMe)2][BF4] while its analogue containing both tertiary amino and carboxylic ester groups [(C17H9(COOMe)N(CH2)4)(C3H5)Mo(CO)2] decomposes under the same conditions. [(C17H10Me)Mo(CO)2(NCMe)2][BF4] reacts with cyclopentadiene to give a stable complex [(C5H6)(C17H10Me)Mo(CO)2][BF4] that was successfully oxidized to the Mo(IV) dicationic compound [(C5H5)(C17H10Me)Mo(CO)2][Br][BF4]. (en)
Title	Molybdenum complexes containing substituted cyclopenta[l]phenanthrenyl ligand Molybdenum complexes containing substituted cyclopenta[l]phenanthrenyl ligand (en)
skos:prefLabel	Molybdenum complexes containing substituted cyclopenta[l]phenanthrenyl ligand Molybdenum complexes containing substituted cyclopenta[l]phenanthrenyl ligand (en)
skos:notation	RIV/00216275:25310/10:39882987!RIV11-GA0-25310___
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(GP203/09/P100), Z(MSM0021627501)
http://linked.open...iv/cisloPeriodika	5
http://linked.open...vai/riv/dodaniDat	2011
http://linked.open...aciTvurceVysledku	Honzíček, Jan
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Univerzita Pardubice / Fakulta chemicko-technologická
http://linked.open...dnocenehoVysledku	272423
http://linked.open...ai/riv/idVysledku	RIV/00216275:25310/10:39882987
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	Molybdenum. (en)
http://linked.open.../riv/klicoveSlovo	Molybdenum.
http://linked.open...odStatuVydavatele	CH - Švýcarská konfederace
http://linked.open...ontrolniKodProRIV	[CF830386F816]
http://linked.open...i/riv/nazevZdroje	Journal of Organometallic Chemistry
http://linked.open...in/vavai/riv/obor	CA
http://linked.open...ichTvurcuVysledku	1 (xsd:int)
http://linked.open...cetTvurcuVysledku	4 (xsd:int)
http://linked.open...vavai/riv/projekt	Ring-functionalized vanadocene and molybdenocene complexes
http://linked.open...UplatneniVysledku	2010
http://linked.open...v/svazekPeriodika	695
http://linked.open...iv/tvurceVysledku	Honzíček, Jan Mukhopadhyay, Abhik Rom?o, Carlos C. Bonifacio, C.
http://linked.open...ain/vavai/riv/wos	000274394100007
http://linked.open...n/vavai/riv/zamer	Aimed preparation of special compounds and materials and investigation of their physical and chemical properties and supramolecular structures
issn	0022-328X
number of pages	7 (xsd:int)
http://localhost/t...ganizacniJednotka	25310

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