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rdf:type
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Description
| - Reaction of vanadocene dichlorides (Cp2VCl2 and (C5H4Me)2VCl2) with amino acids containing secondary amino groups gives three types of complexes: a) compounds with N,O-bonded amino acid, b) O-bonded amino acids and c) O,O-bonded amino acid. The complexes with N,O-bonded amino acid and O-bonded amino acids were observed in the case of L-proline and N-methylglycine (NMG). Reactions with N-phenylglycine (NPG) give O,O-chelates as the sole products. All three types of the complexes were characterized by spectroscopic methods. Structures of [(C5H4Me)2V(O-Pro)][BPh4], [Cp2V(O-Pro)2][PF6]2, [Cp2V(N,O-NMG)][BPh4], [(C5H4Me)2V(N,O-NMG)][BPh4], [Cp2V(O-NMG)2][Cl]2, [(C5H4Me)2V(O-NMG)2][Cl]2 and [(C5H4Me)2V(O,O-NPG)][BPh4] were determined by X-ray crystallography.
- Reaction of vanadocene dichlorides (Cp2VCl2 and (C5H4Me)2VCl2) with amino acids containing secondary amino groups gives three types of complexes: a) compounds with N,O-bonded amino acid, b) O-bonded amino acids and c) O,O-bonded amino acid. The complexes with N,O-bonded amino acid and O-bonded amino acids were observed in the case of L-proline and N-methylglycine (NMG). Reactions with N-phenylglycine (NPG) give O,O-chelates as the sole products. All three types of the complexes were characterized by spectroscopic methods. Structures of [(C5H4Me)2V(O-Pro)][BPh4], [Cp2V(O-Pro)2][PF6]2, [Cp2V(N,O-NMG)][BPh4], [(C5H4Me)2V(N,O-NMG)][BPh4], [Cp2V(O-NMG)2][Cl]2, [(C5H4Me)2V(O-NMG)2][Cl]2 and [(C5H4Me)2V(O,O-NPG)][BPh4] were determined by X-ray crystallography. (en)
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Title
| - Vanadocene complexes of amino acids containing secondary amino group: The first evidence of O,O-bonded carboxylic group to vanadocene(IV) moiety.
- Vanadocene complexes of amino acids containing secondary amino group: The first evidence of O,O-bonded carboxylic group to vanadocene(IV) moiety. (en)
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skos:prefLabel
| - Vanadocene complexes of amino acids containing secondary amino group: The first evidence of O,O-bonded carboxylic group to vanadocene(IV) moiety.
- Vanadocene complexes of amino acids containing secondary amino group: The first evidence of O,O-bonded carboxylic group to vanadocene(IV) moiety. (en)
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skos:notation
| - RIV/00216275:25310/10:39882940!RIV11-GA0-25310___
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http://linked.open...avai/riv/aktivita
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http://linked.open...avai/riv/aktivity
| - P(GA203/09/0460), Z(MSM0021627501)
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http://linked.open...iv/cisloPeriodika
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http://linked.open...vai/riv/dodaniDat
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http://linked.open...aciTvurceVysledku
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http://linked.open.../riv/druhVysledku
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http://linked.open...iv/duvernostUdaju
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http://linked.open...titaPredkladatele
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http://linked.open...dnocenehoVysledku
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http://linked.open...ai/riv/idVysledku
| - RIV/00216275:25310/10:39882940
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http://linked.open...riv/jazykVysledku
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http://linked.open.../riv/klicovaSlova
| - EPR; X-ray; amino acids; vanadocene complexes (en)
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http://linked.open.../riv/klicoveSlovo
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http://linked.open...odStatuVydavatele
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http://linked.open...ontrolniKodProRIV
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http://linked.open...i/riv/nazevZdroje
| - Journal of Inorganic Biochemistry
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http://linked.open...in/vavai/riv/obor
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http://linked.open...ichTvurcuVysledku
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http://linked.open...cetTvurcuVysledku
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http://linked.open...vavai/riv/projekt
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http://linked.open...UplatneniVysledku
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http://linked.open...v/svazekPeriodika
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http://linked.open...iv/tvurceVysledku
| - Růžička, Aleš
- Vinklárek, Jaromír
- Honzíček, Jan
- Dědourková, Tereza
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http://linked.open...ain/vavai/riv/wos
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http://linked.open...n/vavai/riv/zamer
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issn
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number of pages
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http://localhost/t...ganizacniJednotka
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