About: [{2,6-(Me2NCH2)2C6H3(H2O)Sn}W(CO)5]+?CB11H12-: Aqua Complex of a Transition-Metal-Bound Organotin(II) Cation versus an Ammonium-Type Structure,

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About: [{2,6-(Me2NCH2)2C6H3(H2O)Sn}W(CO)5]+?CB11H12-: Aqua Complex of a Transition-Metal-Bound Organotin(II) Cation versus an Ammonium-Type Structure, Goto Sponge NotDistinct Permalink

An Entity of Type : http://linked.opendata.cz/ontology/domain/vavai/Vysledek, within Data Space : linked.opendata.cz associated with source document(s)

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	The molecular structures of the intramolecularly coordinated tungstenpentacarbonyl organostannylene complexes 2,6-(Me2NCH2)2C6H3(Cl)SnW(CO)5 and [2,6-(Me2NCH2)2C6H3(H2O)SnW(CO)5]+(CB11H12)- are reported. The latter compound is an aqua complex in which the water molecule replaces one of the two N?Sn coordination sites. The coordination of the water molecule is accompanied by proton transfer to the nitrogen atom. DFT calculations reveal this to be the thermodynamically most-stable structure. The molecular structures of the intramolecularly coordinated tungstenpentacarbonyl organostannylene complexes 2,6-(Me2NCH2)2C6H3(Cl)SnW(CO)5 and [2,6-(Me2NCH2)2C6H3(H2O)SnW(CO)5]+(CB11H12)- are reported. The latter compound is an aqua complex in which the water molecule replaces one of the two N?Sn coordination sites. The coordination of the water molecule is accompanied by proton transfer to the nitrogen atom. DFT calculations reveal this to be the thermodynamically most-stable structure. (en)
Title	[{2,6-(Me2NCH2)2C6H3(H2O)Sn}W(CO)5]+?CB11H12-: Aqua Complex of a Transition-Metal-Bound Organotin(II) Cation versus an Ammonium-Type Structure, [{2,6-(Me2NCH2)2C6H3(H2O)Sn}W(CO)5]+?CB11H12-: Aqua Complex of a Transition-Metal-Bound Organotin(II) Cation versus an Ammonium-Type Structure, (en)
skos:prefLabel	[{2,6-(Me2NCH2)2C6H3(H2O)Sn}W(CO)5]+?CB11H12-: Aqua Complex of a Transition-Metal-Bound Organotin(II) Cation versus an Ammonium-Type Structure, [{2,6-(Me2NCH2)2C6H3(H2O)Sn}W(CO)5]+?CB11H12-: Aqua Complex of a Transition-Metal-Bound Organotin(II) Cation versus an Ammonium-Type Structure, (en)
skos:notation	RIV/00216275:25310/10:39882028!RIV11-GA0-25310___
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(GAP207/10/0215), Z(MSM0021627501)
http://linked.open...iv/cisloPeriodika	6
http://linked.open...vai/riv/dodaniDat	2011
http://linked.open...aciTvurceVysledku	Kašná, Blanka Jambor, Roman
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Univerzita Pardubice / Fakulta chemicko-technologická
http://linked.open...dnocenehoVysledku	300931
http://linked.open...ai/riv/idVysledku	RIV/00216275:25310/10:39882028
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	Cation; Organotin(II); Transition-Metal-Bound; Aqua Complex (en)
http://linked.open.../riv/klicoveSlovo	Aqua Complex Cation Organotin(II) Transition-Metal-Bound
http://linked.open...odStatuVydavatele	DE - Spolková republika Německo
http://linked.open...ontrolniKodProRIV	[9D35228E01F3]
http://linked.open...i/riv/nazevZdroje	European Journal of Inorganic Chemistry
http://linked.open...in/vavai/riv/obor	CA
http://linked.open...ichTvurcuVysledku	2 (xsd:int)
http://linked.open...cetTvurcuVysledku	6 (xsd:int)
http://linked.open...vavai/riv/projekt	Structure, Properties and the Use of C,N-, Y,C,Y-chelated Organometallic and Related Metal Complexes
http://linked.open...UplatneniVysledku	2010
http://linked.open...v/svazekPeriodika	neuveden
http://linked.open...iv/tvurceVysledku	Jambor, Roman Kašná, Blanka Jurkschat, K. Koller, S. Schurmann, M. Strohmann, C.
http://linked.open...ain/vavai/riv/wos	000275240500009
http://linked.open...n/vavai/riv/zamer	Aimed preparation of special compounds and materials and investigation of their physical and chemical properties and supramolecular structures
issn	1434-1948
number of pages	7 (xsd:int)
http://localhost/t...ganizacniJednotka	25310

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