About: Structural study on the organoantimony(III) NCN - Chelated compounds [2,6-(Me2NCH2)2C6H3]SbX2

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About: Structural study on the organoantimony(III) NCN - Chelated compounds [2,6-(Me2NCH2)2C6H3]SbX2 - Influence of the polar group X Goto Sponge NotDistinct Permalink

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	It was demonstrated that the behaviour of polar group X in the compounds of the type [2,6-(Me2NCH2)2C6H3]SbX2 has a crucial effect on the geometry around the central antimony atom. The shapes of coordination polyhedron range from a bicapped - trigonal pyramid (X = CH3COO), and a distorted tetragonal pyramid (X = CF3COO) to a psí-trigonal bipyramid (X = Cl, CB11H12). Even more, an unusual dinuclear ionic complex was prepared and characterized and in this case the structure of the organometallic cation can be described as one apex sharing distorted tetragonal pyramids. It was demonstrated that the behaviour of polar group X in the compounds of the type [2,6-(Me2NCH2)2C6H3]SbX2 has a crucial effect on the geometry around the central antimony atom. The shapes of coordination polyhedron range from a bicapped - trigonal pyramid (X = CH3COO), and a distorted tetragonal pyramid (X = CF3COO) to a psí-trigonal bipyramid (X = Cl, CB11H12). Even more, an unusual dinuclear ionic complex was prepared and characterized and in this case the structure of the organometallic cation can be described as one apex sharing distorted tetragonal pyramids. (en)
Title	Structural study on the organoantimony(III) NCN - Chelated compounds [2,6-(Me2NCH2)2C6H3]SbX2 - Influence of the polar group X Structural study on the organoantimony(III) NCN - Chelated compounds [2,6-(Me2NCH2)2C6H3]SbX2 - Influence of the polar group X (en)
skos:prefLabel	Structural study on the organoantimony(III) NCN - Chelated compounds [2,6-(Me2NCH2)2C6H3]SbX2 - Influence of the polar group X Structural study on the organoantimony(III) NCN - Chelated compounds [2,6-(Me2NCH2)2C6H3]SbX2 - Influence of the polar group X (en)
skos:notation	RIV/00216275:25310/10:39881463!RIV11-GA0-25310___
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(GP203/07/P094), Z(MSM0021627501), Z(MSM0021627502)
http://linked.open...iv/cisloPeriodika	3
http://linked.open...vai/riv/dodaniDat	2011
http://linked.open...aciTvurceVysledku	Dostál, Libor Růžička, Aleš Padělková, Zdeňka Jambor, Roman Jirásko, Robert Holeček, Jaroslav
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Univerzita Pardubice / Fakulta chemicko-technologická
http://linked.open...dnocenehoVysledku	290453
http://linked.open...ai/riv/idVysledku	RIV/00216275:25310/10:39881463
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	group; polar; the; Influence; [2,6-(Me2NCH2)2C6H3]SbX2; compounds; Chelated; NCN; organoantimony(III); the; study; Structural (en)
http://linked.open.../riv/klicoveSlovo	Influence study polar the group Structural compounds [2 6-(Me2NCH2)2C6H3]SbX2 Chelated NCN organoantimony(III)
http://linked.open...odStatuVydavatele	CH - Švýcarská konfederace
http://linked.open...ontrolniKodProRIV	[0825F3DAB194]
http://linked.open...i/riv/nazevZdroje	Journal of Organometallic Chemistry
http://linked.open...in/vavai/riv/obor	CA
http://linked.open...ichTvurcuVysledku	6 (xsd:int)
http://linked.open...cetTvurcuVysledku	6 (xsd:int)
http://linked.open...vavai/riv/projekt	Organoantimony(III) and organobismuth(III) compounds containing O,C,O chelating ligands
http://linked.open...UplatneniVysledku	2010
http://linked.open...v/svazekPeriodika	695
http://linked.open...iv/tvurceVysledku	Dostál, Libor Jambor, Roman Padělková, Zdeňka Růžička, Aleš Jirásko, Robert Holeček, Jaroslav
http://linked.open...ain/vavai/riv/wos	000273782000012
http://linked.open...n/vavai/riv/zamer	Aimed preparation of special compounds and materials and investigation of their physical and chemical properties and supramolecular structures Pokročilé analytické a separační metody a jejich aplikace v diagnostice a technologii živých a neživých materiálů
issn	0022-328X
number of pages	6 (xsd:int)
http://localhost/t...ganizacniJednotka	25310

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