About: One-step and solvent-free synthesis of terpene-fused pyrazines     Goto   Sponge   NotDistinct   Permalink

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Description
  • Solvent-free condensation reactions were carried out by heating terpene-monooximes with an excess of amines. Employing camphor- and nopinone-derived monooximes, two classes of terpene-fused pyrazine derivatives were synthesized. Besides being solvent-free, the described one-step procedure can be directed towards terpene-fused imidazole or pyrazine derivatives. Whereas the reaction worked well with arylmethanamines bearing a (hetero)aromatic substituent at the alfa-carbon, alkylamines afforded only imino-oximes. A possible reaction path is presented.
  • Solvent-free condensation reactions were carried out by heating terpene-monooximes with an excess of amines. Employing camphor- and nopinone-derived monooximes, two classes of terpene-fused pyrazine derivatives were synthesized. Besides being solvent-free, the described one-step procedure can be directed towards terpene-fused imidazole or pyrazine derivatives. Whereas the reaction worked well with arylmethanamines bearing a (hetero)aromatic substituent at the alfa-carbon, alkylamines afforded only imino-oximes. A possible reaction path is presented. (en)
Title
  • One-step and solvent-free synthesis of terpene-fused pyrazines
  • One-step and solvent-free synthesis of terpene-fused pyrazines (en)
skos:prefLabel
  • One-step and solvent-free synthesis of terpene-fused pyrazines
  • One-step and solvent-free synthesis of terpene-fused pyrazines (en)
skos:notation
  • RIV/00216275:25310/10:39881344!RIV11-MSM-25310___
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(LA09041), Z(MSM0021627501)
http://linked.open...iv/cisloPeriodika
  • 2010
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 276985
http://linked.open...ai/riv/idVysledku
  • RIV/00216275:25310/10:39881344
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • terpene; pyrazine; solvent-free; synthesis (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • US - Spojené státy americké
http://linked.open...ontrolniKodProRIV
  • [7A00642F534B]
http://linked.open...i/riv/nazevZdroje
  • ARKIVOC
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • Part 2
http://linked.open...iv/tvurceVysledku
  • Bureš, Filip
  • Kulhánek, Jiří
  • Ludwig, Miroslav
http://linked.open...ain/vavai/riv/wos
  • 000280582800026
http://linked.open...n/vavai/riv/zamer
issn
  • 1424-6376
number of pages
http://localhost/t...ganizacniJednotka
  • 25310
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