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  • New procedures of potentiometric stripping analysis can be based on the use of antimony film electrodes and antimony(III) salts. In this paper, antimony films are generated onto carbon paste electrodes in situ and after electrolytic preconcentration of the metals to be determined, the excess antimony(III) serves as a chemical oxidant. Moreover in acidic solutions containing halide ions, the oxidation ability of antimony(III) is adequately limited because of formation of its corresponding halide complexes. Compared with similar total substitution of traditionally used mercury(II) by bismuth(III), the use of antimony(III) offers higher sensitivity in detection of heavy metals, namely, cadmium and lead.
  • New procedures of potentiometric stripping analysis can be based on the use of antimony film electrodes and antimony(III) salts. In this paper, antimony films are generated onto carbon paste electrodes in situ and after electrolytic preconcentration of the metals to be determined, the excess antimony(III) serves as a chemical oxidant. Moreover in acidic solutions containing halide ions, the oxidation ability of antimony(III) is adequately limited because of formation of its corresponding halide complexes. Compared with similar total substitution of traditionally used mercury(II) by bismuth(III), the use of antimony(III) offers higher sensitivity in detection of heavy metals, namely, cadmium and lead. (en)
Title
  • Potentiometric stripping analysis with antimony film electrodes
  • Potentiometric stripping analysis with antimony film electrodes (en)
skos:prefLabel
  • Potentiometric stripping analysis with antimony film electrodes
  • Potentiometric stripping analysis with antimony film electrodes (en)
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  • RIV/00216275:25310/09:00008407!RIV10-MSM-25310___
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(LC06035), Z(MSM0021627502)
http://linked.open...iv/cisloPeriodika
  • 9
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
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  • 334821
http://linked.open...ai/riv/idVysledku
  • RIV/00216275:25310/09:00008407
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • stripping potentiometry; antimony film electrodes; antimony(III); carbon paste electrodes; heavy metals determination (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • DE - Spolková republika Německo
http://linked.open...ontrolniKodProRIV
  • [6CBE81349E6D]
http://linked.open...i/riv/nazevZdroje
  • Electroanalysis
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
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http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 21
http://linked.open...iv/tvurceVysledku
  • Tesařová, Eva
  • Vytřas, Karel
http://linked.open...n/vavai/riv/zamer
issn
  • 1040-0397
number of pages
http://localhost/t...ganizacniJednotka
  • 25310
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