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  • The antimony film carbon paste electrode (SbF-CPE) was prepared in situ on the carbon paste substrate electrode as a %22mercury-free%22 electrochemical sensor. Its aptitude for measuring some selected heavy metals has been demonstrated in combination with square-wave anodic stripping voltammetry in non-deaerated model solutions of 0.01 M hydrochloric acid with pH 2. Some important operational parameters, such as deposition potential, deposition time, and concentration of antimony ions were optimized, and the electroanalytical performance of the SbF-CPE was critically compared with both bismuth film carbon paste electrode (BiF-CPE) and mercury film carbon paste electrode (MF-CPE) using Cd(II) and Pb(II) as test metal ions.
  • The antimony film carbon paste electrode (SbF-CPE) was prepared in situ on the carbon paste substrate electrode as a %22mercury-free%22 electrochemical sensor. Its aptitude for measuring some selected heavy metals has been demonstrated in combination with square-wave anodic stripping voltammetry in non-deaerated model solutions of 0.01 M hydrochloric acid with pH 2. Some important operational parameters, such as deposition potential, deposition time, and concentration of antimony ions were optimized, and the electroanalytical performance of the SbF-CPE was critically compared with both bismuth film carbon paste electrode (BiF-CPE) and mercury film carbon paste electrode (MF-CPE) using Cd(II) and Pb(II) as test metal ions. (en)
Title
  • Anodic stripping voltammetric measurement of trace heavy metals at antimony film carbon paste electrode
  • Anodic stripping voltammetric measurement of trace heavy metals at antimony film carbon paste electrode (en)
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  • Anodic stripping voltammetric measurement of trace heavy metals at antimony film carbon paste electrode
  • Anodic stripping voltammetric measurement of trace heavy metals at antimony film carbon paste electrode (en)
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  • RIV/00216275:25310/09:00008401!RIV10-MSM-25310___
http://linked.open...avai/riv/aktivita
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  • P(LC06035), Z(MSM0021627502)
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  • 5
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  • 303394
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  • RIV/00216275:25310/09:00008401
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  • carbon paste electrode; heavy metals; antimony film; anodic stripping voltammetry (en)
http://linked.open.../riv/klicoveSlovo
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  • GB - Spojené království Velké Británie a Severního Irska
http://linked.open...ontrolniKodProRIV
  • [FC27F08C71F5]
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  • Electrochimica Acta
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  • 54
http://linked.open...iv/tvurceVysledku
  • Baldrianová, Lucie
  • Ogorevc, Božidar
  • Tesařová, Eva
  • Vytřas, Karel
  • Švancara, Ivan
  • Hočevar, Samo B
http://linked.open...n/vavai/riv/zamer
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  • 0013-4686
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  • 25310
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