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Description
| - The acid-catalyzed decomposition of unusually stable 1-(2,1-benzisothiazol-3-yl)-3-phenyltriazenes in either aqueous perchloric acid or an aqueous mixture of perchloric and acetic acid was studied under pseudo-first order reaction conditions at 25 degrees C. Different products were obtained according to substitution on nitrogen N-3. An A-S(E)2 mechanism in which protonation of the triazene nitrogen proceeds simultaneously with cleavage of the N-N bond is proposed. Tautomerism of 1-(2,1-benzisothiazol-3-yl)3-phenyltriazene was investigated using H-1 NMR spectroscopy.
- The acid-catalyzed decomposition of unusually stable 1-(2,1-benzisothiazol-3-yl)-3-phenyltriazenes in either aqueous perchloric acid or an aqueous mixture of perchloric and acetic acid was studied under pseudo-first order reaction conditions at 25 degrees C. Different products were obtained according to substitution on nitrogen N-3. An A-S(E)2 mechanism in which protonation of the triazene nitrogen proceeds simultaneously with cleavage of the N-N bond is proposed. Tautomerism of 1-(2,1-benzisothiazol-3-yl)3-phenyltriazene was investigated using H-1 NMR spectroscopy. (en)
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Title
| - Acid-catalyzed decomposition of stable 1-(2,1-benzisothiazol-3-yl)-3-phenyltriazenes
- Acid-catalyzed decomposition of stable 1-(2,1-benzisothiazol-3-yl)-3-phenyltriazenes (en)
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skos:prefLabel
| - Acid-catalyzed decomposition of stable 1-(2,1-benzisothiazol-3-yl)-3-phenyltriazenes
- Acid-catalyzed decomposition of stable 1-(2,1-benzisothiazol-3-yl)-3-phenyltriazenes (en)
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skos:notation
| - RIV/00216275:25310/09:00008356!RIV10-MSM-25310___
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http://linked.open...avai/riv/aktivita
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http://linked.open...avai/riv/aktivity
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http://linked.open...iv/cisloPeriodika
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http://linked.open...vai/riv/dodaniDat
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http://linked.open...aciTvurceVysledku
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http://linked.open.../riv/druhVysledku
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http://linked.open...iv/duvernostUdaju
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http://linked.open...titaPredkladatele
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http://linked.open...dnocenehoVysledku
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http://linked.open...ai/riv/idVysledku
| - RIV/00216275:25310/09:00008356
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http://linked.open...riv/jazykVysledku
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http://linked.open.../riv/klicovaSlova
| - 1-(2,1-Benzisothiazol-3-yl)-3-phenyltriazenes; Acid-catalyzed decomposition; automerism; Mechanism; Kinetics (en)
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http://linked.open.../riv/klicoveSlovo
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http://linked.open...odStatuVydavatele
| - GB - Spojené království Velké Británie a Severního Irska
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http://linked.open...ontrolniKodProRIV
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http://linked.open...i/riv/nazevZdroje
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http://linked.open...in/vavai/riv/obor
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http://linked.open...ichTvurcuVysledku
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http://linked.open...cetTvurcuVysledku
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http://linked.open...UplatneniVysledku
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http://linked.open...v/svazekPeriodika
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http://linked.open...iv/tvurceVysledku
| - Hanusek, Jiří
- Macháček, Vladimír
- Přikryl, Josef
- Bělohlavová, Hana
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http://linked.open...n/vavai/riv/zamer
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issn
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number of pages
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http://localhost/t...ganizacniJednotka
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