About: The stannylene {2,6-(Me2NCH2)(2)C6H3} SnCl as a Ligand in Transition Metal Complexes of Palladium, Ruthenium, Rhodium

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About: The stannylene {2,6-(Me2NCH2)(2)C6H3} SnCl as a Ligand in Transition Metal Complexes of Palladium, Ruthenium, Rhodium Goto Sponge NotDistinct Permalink

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	The cleavage of the chloride bridge in the dimeric transition complexes [(η3-C3H5)Pd]2(μ-Cl)2, [(η6-benzene)RuCl]2(μ-Cl)2, [(η6-cymene)RuCl]2(μ-Cl)2, [(CΟ)3RuCl]2(μ-Cl)2, and [(CΟ)2Rh]2(μ-Cl)2 by heteroleptic LSnCl stannylene (L is a N,C,N-pincer ligand [2,6-(Me2NCH2)2C6H3]) resulted in the isolation of PdII-SnII, RuII-SnII, and RhI-SnII complexes [Pd(η3-C3H5)(LSnCl)Cl] (2), [Ru(η6-benzene)(LSnCl)Cl2] (3), [Ru(η6-cymene)(LSnCl)Cl2] (4), [Ru(CO)3(LSnCl)Cl2] (5), and [Rh-(CO)2(LSnCl)Cl] (6). All compounds were characterized by NMR and IR spectroscopy, and the structures of compounds 2 and 4 were determined by X-ray diffraction analysis. The structure of a rare monomeric RhII-SnII complex, [Rh(LSnCl)2Cl2] (7), the final decomposition product of RhI-SnII complex 6, is also reported. The cleavage of the chloride bridge in the dimeric transition complexes [(η3-C3H5)Pd]2(μ-Cl)2, [(η6-benzene)RuCl]2(μ-Cl)2, [(η6-cymene)RuCl]2(μ-Cl)2, [(CΟ)3RuCl]2(μ-Cl)2, and [(CΟ)2Rh]2(μ-Cl)2 by heteroleptic LSnCl stannylene (L is a N,C,N-pincer ligand [2,6-(Me2NCH2)2C6H3]) resulted in the isolation of PdII-SnII, RuII-SnII, and RhI-SnII complexes [Pd(η3-C3H5)(LSnCl)Cl] (2), [Ru(η6-benzene)(LSnCl)Cl2] (3), [Ru(η6-cymene)(LSnCl)Cl2] (4), [Ru(CO)3(LSnCl)Cl2] (5), and [Rh-(CO)2(LSnCl)Cl] (6). All compounds were characterized by NMR and IR spectroscopy, and the structures of compounds 2 and 4 were determined by X-ray diffraction analysis. The structure of a rare monomeric RhII-SnII complex, [Rh(LSnCl)2Cl2] (7), the final decomposition product of RhI-SnII complex 6, is also reported. (en)
Title	The stannylene {2,6-(Me2NCH2)(2)C6H3} SnCl as a Ligand in Transition Metal Complexes of Palladium, Ruthenium, Rhodium The stannylene {2,6-(Me2NCH2)(2)C6H3} SnCl as a Ligand in Transition Metal Complexes of Palladium, Ruthenium, Rhodium (en)
skos:prefLabel	The stannylene {2,6-(Me2NCH2)(2)C6H3} SnCl as a Ligand in Transition Metal Complexes of Palladium, Ruthenium, Rhodium The stannylene {2,6-(Me2NCH2)(2)C6H3} SnCl as a Ligand in Transition Metal Complexes of Palladium, Ruthenium, Rhodium (en)
skos:notation	RIV/00216275:25310/09:00008340!RIV10-MSM-25310___
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(GA203/07/0468), P(LC523), Z(MSM0021627501)
http://linked.open...iv/cisloPeriodika	16
http://linked.open...vai/riv/dodaniDat	2010
http://linked.open...aciTvurceVysledku	Dostál, Libor Růžička, Aleš Jambor, Roman
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Univerzita Pardubice / Fakulta chemicko-technologická
http://linked.open...dnocenehoVysledku	343414
http://linked.open...ai/riv/idVysledku	RIV/00216275:25310/09:00008340
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	stannylene; chelating ligand; transition metals complexes (en)
http://linked.open.../riv/klicoveSlovo	stannylene chelating ligand transition metals complexes
http://linked.open...odStatuVydavatele	US - Spojené státy americké
http://linked.open...ontrolniKodProRIV	[D9AE2EE22086]
http://linked.open...i/riv/nazevZdroje	Organometallics
http://linked.open...in/vavai/riv/obor	CA
http://linked.open...ichTvurcuVysledku	3 (xsd:int)
http://linked.open...cetTvurcuVysledku	5 (xsd:int)
http://linked.open...vavai/riv/projekt	Perspective inorganic materials Study of properties and the use of C,N- and Y,C,Y-chelated organometallic compounds
http://linked.open...UplatneniVysledku	2009
http://linked.open...v/svazekPeriodika	28
http://linked.open...iv/tvurceVysledku	Dostál, Libor Dostálová, Romana Jambor, Roman Růžička, Aleš Martincová, Jana
http://linked.open...n/vavai/riv/zamer	Aimed preparation of special compounds and materials and investigation of their physical and chemical properties and supramolecular structures
issn	0276-7333
number of pages	6 (xsd:int)
http://localhost/t...ganizacniJednotka	25310

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