About: Thermal Properties and Stability of Lithium Titanophosphate     Goto   Sponge   NotDistinct   Permalink

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  • DTA was used to study thermal properties and thermal stability of (50-x)Li2O-xTiO2-50P2O5 (x=0-10 mol%) and 45Li2O-yTiO2-(55-y)P2O5 (y=5-20 mol%) glasses. The addition of TiO2 to lithium phosphate glasses results in a non-linear increase of glass transition temperature. All prepared glasses crystallize under heating within the temperature range of 400-540°C. The lowest tendency towards crystallization have the glasses with x=7.5 and y=10 mol% TiO2. X-ray diffraction analysis showed that major compounds formed by annealing of the glasses were LiPO3, Li4P2O7, TiP2O7 and NASICON-type LiTi2(PO4)3. DTA results also indicated that the maximum of nucleation rate for 45Li2O-5TiO2-50P2O5 glass is close to the glass transition temperature.
  • DTA was used to study thermal properties and thermal stability of (50-x)Li2O-xTiO2-50P2O5 (x=0-10 mol%) and 45Li2O-yTiO2-(55-y)P2O5 (y=5-20 mol%) glasses. The addition of TiO2 to lithium phosphate glasses results in a non-linear increase of glass transition temperature. All prepared glasses crystallize under heating within the temperature range of 400-540°C. The lowest tendency towards crystallization have the glasses with x=7.5 and y=10 mol% TiO2. X-ray diffraction analysis showed that major compounds formed by annealing of the glasses were LiPO3, Li4P2O7, TiP2O7 and NASICON-type LiTi2(PO4)3. DTA results also indicated that the maximum of nucleation rate for 45Li2O-5TiO2-50P2O5 glass is close to the glass transition temperature. (en)
Title
  • Thermal Properties and Stability of Lithium Titanophosphate
  • Thermal Properties and Stability of Lithium Titanophosphate (en)
skos:prefLabel
  • Thermal Properties and Stability of Lithium Titanophosphate
  • Thermal Properties and Stability of Lithium Titanophosphate (en)
skos:notation
  • RIV/00216275:25310/09:00008333!RIV10-MSM-25310___
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(GA104/07/0315), Z(MSM0021627501)
http://linked.open...iv/cisloPeriodika
  • 1
http://linked.open...vai/riv/dodaniDat
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  • 346218
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  • RIV/00216275:25310/09:00008333
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  • phosphate glasses; thermal properties; thermal stability; titanium oxide (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • NL - Nizozemsko
http://linked.open...ontrolniKodProRIV
  • [7825B09F672A]
http://linked.open...i/riv/nazevZdroje
  • Journal of Thermal Analysis and Calorimetry (Paper)
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http://linked.open...ichTvurcuVysledku
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http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 95
http://linked.open...iv/tvurceVysledku
  • Koudelka, Ladislav
  • Mošner, Petr
  • Vosejpková, Kateřina
http://linked.open...n/vavai/riv/zamer
issn
  • 1388-6150
number of pages
http://localhost/t...ganizacniJednotka
  • 25310
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