About: Reactivity of C,N-Chelated Stannylene with Azobenzene     Goto   Sponge   NotDistinct   Permalink

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  • The reactivity of a C,N-chelated stannylene L2Sn [L=2-(Me2NCH2)C6H4] with azobenzene yielded two different products. In the case of reaction in diethyl ether at room temperature, the cyclic complex L2Sn-N(Ph)-N(Ph)-SnL2 was isolated. The second compound, isolated from the reaction in boiling THF, is the product of C-H activation and orthometallation of azobenzene, the cyclic [2-(SnL2)-C6H4]-N-N-[C6H4-2-(SnL2)]. Byproducts in the second reaction are the free ligand (LH) and the cyclic complex L2Sn-(L)Sn-Sn(L)(2)-O(H).
  • The reactivity of a C,N-chelated stannylene L2Sn [L=2-(Me2NCH2)C6H4] with azobenzene yielded two different products. In the case of reaction in diethyl ether at room temperature, the cyclic complex L2Sn-N(Ph)-N(Ph)-SnL2 was isolated. The second compound, isolated from the reaction in boiling THF, is the product of C-H activation and orthometallation of azobenzene, the cyclic [2-(SnL2)-C6H4]-N-N-[C6H4-2-(SnL2)]. Byproducts in the second reaction are the free ligand (LH) and the cyclic complex L2Sn-(L)Sn-Sn(L)(2)-O(H). (en)
Title
  • Reactivity of C,N-Chelated Stannylene with Azobenzene
  • Reactivity of C,N-Chelated Stannylene with Azobenzene (en)
skos:prefLabel
  • Reactivity of C,N-Chelated Stannylene with Azobenzene
  • Reactivity of C,N-Chelated Stannylene with Azobenzene (en)
skos:notation
  • RIV/00216275:25310/09:00008300!RIV10-MSM-25310___
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(GA203/07/0468), P(KJB401550802), Z(MSM0021627501)
http://linked.open...iv/cisloPeriodika
  • 14
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 338213
http://linked.open...ai/riv/idVysledku
  • RIV/00216275:25310/09:00008300
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • C,N-Chelated Stannylene; Azobenzene (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • DE - Spolková republika Německo
http://linked.open...ontrolniKodProRIV
  • [9CAB5D0159F4]
http://linked.open...i/riv/nazevZdroje
  • European Journal of Inorganic Chemistry
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • N
http://linked.open...iv/tvurceVysledku
  • Holubová, Jana
  • Padělková, Zdeňka
  • Růžička, Aleš
  • Lyčka, Antonín
  • Nechaev, Mikhail S.
  • Zevaco, Thomas A.
http://linked.open...n/vavai/riv/zamer
issn
  • 1434-1948
number of pages
http://localhost/t...ganizacniJednotka
  • 25310
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