About: Structure of 2:1 Cobalt(III) Complexes Derived from Arylazocitrazinic Acid     Goto   Sponge   NotDistinct   Permalink

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  • 1H, 13C NMR and MS spectra of the 2:1 cobalt(III) complexes derived the azo coupling products of 2-aminophenol or 2-aminobenzoic acid with the citrazinic acid were measured and analysed. It was found that the cobalt atom is six-coordinated being bound to two oxygens (one from primary and one from secondary component) and the nitrogen of 2-aminophenol or 2-aminobenzoic acid. Molar magnetic susceptibility data proved the presence of Co(III). Diazotisation of 2-aminophenol or 2-aminobenzoic acid and subsequent coupling reaction with citrazinic acid and complexation of the formed azo product proceeded on standard way.
  • 1H, 13C NMR and MS spectra of the 2:1 cobalt(III) complexes derived the azo coupling products of 2-aminophenol or 2-aminobenzoic acid with the citrazinic acid were measured and analysed. It was found that the cobalt atom is six-coordinated being bound to two oxygens (one from primary and one from secondary component) and the nitrogen of 2-aminophenol or 2-aminobenzoic acid. Molar magnetic susceptibility data proved the presence of Co(III). Diazotisation of 2-aminophenol or 2-aminobenzoic acid and subsequent coupling reaction with citrazinic acid and complexation of the formed azo product proceeded on standard way. (en)
Title
  • Structure of 2:1 Cobalt(III) Complexes Derived from Arylazocitrazinic Acid
  • Structure of 2:1 Cobalt(III) Complexes Derived from Arylazocitrazinic Acid (en)
skos:prefLabel
  • Structure of 2:1 Cobalt(III) Complexes Derived from Arylazocitrazinic Acid
  • Structure of 2:1 Cobalt(III) Complexes Derived from Arylazocitrazinic Acid (en)
skos:notation
  • RIV/00216275:25310/09:00008296!RIV10-MSM-25310___
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • Z(MSM0021627501), Z(MSM0021627502)
http://linked.open...iv/cisloPeriodika
  • 4
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
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  • 344223
http://linked.open...ai/riv/idVysledku
  • RIV/00216275:25310/09:00008296
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • Citrazinic acid; complexation; Co(III) complexes; NMR; MS (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • CZ - Česká republika
http://linked.open...ontrolniKodProRIV
  • [90CE82863859]
http://linked.open...i/riv/nazevZdroje
  • Collection of Czechoslovak Chemical Cimmunications
http://linked.open...in/vavai/riv/obor
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http://linked.open...v/svazekPeriodika
  • 74
http://linked.open...iv/tvurceVysledku
  • Hrdina, Radim
  • Jirásko, Robert
  • Lyčka, Antonín
  • Nádvorník, Milan
  • Kořínková, Jaroslava
  • Cee, Aleš
http://linked.open...n/vavai/riv/zamer
issn
  • 0010-0765
number of pages
http://localhost/t...ganizacniJednotka
  • 25310
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