About: Dibromido[bis(η5-cyclopentadienyl)dimethylsilane]zirconium(IV)     Goto   Sponge   NotDistinct   Permalink

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Description
  • The title molecule, [ZrBr2(C12H14Si)], possesses a crystallographically imposed twofold rotational symmetry with the rotation axis passing through the Zr and Si atoms. The ZrIV centre is in a distorted tetrahedral environment defined by two Cp rings of chelating organic ligands and two Br anions. Two five-membered rings form a dihedral angle of 59.7 (2). Unequal Zr-C bonds [2.471 (3), 2.556 (3) A ] in the molecule indicate that the interaction of the central metal with the [(C5H4)2SiMe2]2 ligand contains noticeable eta3-allyl and eta2- olefin contributions.
  • The title molecule, [ZrBr2(C12H14Si)], possesses a crystallographically imposed twofold rotational symmetry with the rotation axis passing through the Zr and Si atoms. The ZrIV centre is in a distorted tetrahedral environment defined by two Cp rings of chelating organic ligands and two Br anions. Two five-membered rings form a dihedral angle of 59.7 (2). Unequal Zr-C bonds [2.471 (3), 2.556 (3) A ] in the molecule indicate that the interaction of the central metal with the [(C5H4)2SiMe2]2 ligand contains noticeable eta3-allyl and eta2- olefin contributions. (en)
Title
  • Dibromido[bis(η5-cyclopentadienyl)dimethylsilane]zirconium(IV)
  • Dibromido[bis(η5-cyclopentadienyl)dimethylsilane]zirconium(IV) (en)
skos:prefLabel
  • Dibromido[bis(η5-cyclopentadienyl)dimethylsilane]zirconium(IV)
  • Dibromido[bis(η5-cyclopentadienyl)dimethylsilane]zirconium(IV) (en)
skos:notation
  • RIV/00216275:25310/09:00008254!RIV10-MSM-25310___
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • Z(MSM0021627501)
http://linked.open...iv/cisloPeriodika
  • 1
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 310268
http://linked.open...ai/riv/idVysledku
  • RIV/00216275:25310/09:00008254
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • single-crystal X-ray study (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • DK - Dánské království
http://linked.open...ontrolniKodProRIV
  • [2452A22697E9]
http://linked.open...i/riv/nazevZdroje
  • Acta Crystallographica Section E - Structure Reports Online
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 65
http://linked.open...iv/tvurceVysledku
  • Dušek, Michal
  • Erben, Milan
  • Vinklárek, Jaromír
  • Picka, Michal
http://linked.open...n/vavai/riv/zamer
issn
  • 1600-5368
number of pages
http://localhost/t...ganizacniJednotka
  • 25310
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