About: Some Properties of Explosive Mixtures Containing Peroxides. Part II. Relationships between Detonation Parameters and Thermal Reactivity of the Mixtures with Triacetone Triperoxide     Goto   Sponge   NotDistinct   Permalink

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  • Studie pojednává o směsích triacetontriperoxidu (3,3,6,6,9,9-hexamethyl-1,2,4,5,7,8-hexoxonan, TATP) s dusičnanem amonným (AN) s přídavkem vody (W), a v některých případech také o suchých směsích TATP s dusičnanem amonným (UN). Relativní pracovní schopnost (RP) těchto směsí a jejich individuálních komponent, vztažená k TNT, byla stanovena balistickým moždířem. Tepelná reaktivita těchto směsí byla specifikována pomocí diferenční termické analýzy (DTA) s analýzou výstupů modifikovanou Kissingerovou metodou (zde píkové teploty exotermického rozkladu byly nahrazeny teplotami počátků tohoto rozkladu). Uvedená reaktivita, vyjádřena směrnicí EaR-1 Kissingerova vztahu, koreluje se čtverci detonační rychlosti pro nábojové hustoty 1000 kgm-3 studovaných směsí. Podobně vztah mezi EaR-1 a RP hodnotami byl nalezen. Zatím co první uvedený vztah (modifikovaná Evans?Polanyi?Semenovova rovnice) souvisí s primárním chemickým mikro-mechanizmem detonace studovaných směsí, vztahy v druhém případě by měly souviset s termo (cs)
  • This study concerns mixtures of triacetone triperoxide (3,3,6,6,9,9-hexamethyl-1,2,4,5,7,8-hexoxonane, TATP) and ammonium nitrate (AN) with added water (W), as the case may be, and two dry mixtures of TATP with urea nitrate (UN). Relative performances (RP) of the mixtures and their individual components, relative to TNT, were determined by means of ballistic mortar. Thermal reactivity of these mixtures was examined by means of differential thermal analysis and the data were analyzed according to the modified Kissinger method (the peak temperature was replaced by the temperature of decomposition onset in this case). The reactivity, expressed as the EaR-1 slopes of the Kissinger relationship, correlates with the squares of the calculated detonation velocities for the charge density of 1000 kgm-3 of the studied energetic materials. Similarly, the relationships between the EaR-1 values and RP have been found. While the first mentioned correlation (modified Evans?Polanyi?Semenov equation) is connected with
  • This study concerns mixtures of triacetone triperoxide (3,3,6,6,9,9-hexamethyl-1,2,4,5,7,8-hexoxonane, TATP) and ammonium nitrate (AN) with added water (W), as the case may be, and two dry mixtures of TATP with urea nitrate (UN). Relative performances (RP) of the mixtures and their individual components, relative to TNT, were determined by means of ballistic mortar. Thermal reactivity of these mixtures was examined by means of differential thermal analysis and the data were analyzed according to the modified Kissinger method (the peak temperature was replaced by the temperature of decomposition onset in this case). The reactivity, expressed as the EaR-1 slopes of the Kissinger relationship, correlates with the squares of the calculated detonation velocities for the charge density of 1000 kgm-3 of the studied energetic materials. Similarly, the relationships between the EaR-1 values and RP have been found. While the first mentioned correlation (modified Evans?Polanyi?Semenov equation) is connected with (en)
Title
  • Some Properties of Explosive Mixtures Containing Peroxides. Part II. Relationships between Detonation Parameters and Thermal Reactivity of the Mixtures with Triacetone Triperoxide
  • Some Properties of Explosive Mixtures Containing Peroxides. Part II. Relationships between Detonation Parameters and Thermal Reactivity of the Mixtures with Triacetone Triperoxide (en)
  • Některé vlastnosti výbušných směsí, obsahujících peroxidy. Část II: Vztah mezi parametry detonace a tepelnou reaktivitou směsí s trioacetontriperoxidem (cs)
skos:prefLabel
  • Some Properties of Explosive Mixtures Containing Peroxides. Part II. Relationships between Detonation Parameters and Thermal Reactivity of the Mixtures with Triacetone Triperoxide
  • Some Properties of Explosive Mixtures Containing Peroxides. Part II. Relationships between Detonation Parameters and Thermal Reactivity of the Mixtures with Triacetone Triperoxide (en)
  • Některé vlastnosti výbušných směsí, obsahujících peroxidy. Část II: Vztah mezi parametry detonace a tepelnou reaktivitou směsí s trioacetontriperoxidem (cs)
skos:notation
  • RIV/00216275:25310/08:00007935!RIV09-MSM-25310___
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • S, Z(MSM0021627501)
http://linked.open...iv/cisloPeriodika
  • 1-3
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 395921
http://linked.open...ai/riv/idVysledku
  • RIV/00216275:25310/08:00007935
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • Ammonium nitrate; Detonation; Differential thermal analysis; Relative performance; Triacetone triperoxide; Urea nitrate (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • NL - Nizozemsko
http://linked.open...ontrolniKodProRIV
  • [828FFB53C4C3]
http://linked.open...i/riv/nazevZdroje
  • Journal of Hazardous Materials
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 0
http://linked.open...iv/tvurceVysledku
  • Zeman, Svatopluk
  • Bartei, Cécile
http://linked.open...n/vavai/riv/zamer
issn
  • 0304-3894
number of pages
http://localhost/t...ganizacniJednotka
  • 25310
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